A beaker with 125 ml. of an acetic acid buffer with a pH of 5.000 is sitting on a benchtop. The total molarity of acid and conjugate base in this buffer is 0.100 M. A student adds 9.00 ml. of a 0.310 M HCT solution to the beaker. How much will the pH change? The pK, of acetic acid is 4.740. Express your answer numerically to two decimal places. Use a minus (-) sign if the pit has decreased.

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Chapter1: Chemical Foundations
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Learning Goal:
To understand how buffers use reserves of
conjugate acid and conjugate base to counteract
the effects of acid or base addition on pH.
A buffer is a mixture of a conjugate acid-base pair
In other words, it is a solution that contains a weak
acid and its conjugate base, or a weak base and its
conjugate acid. For example, an acetic acid buffer
consists of acetic acid, CH₂COOH, and its i
conjugate base, the acetate ion CH, COO
Because ions cannot simply be added to a solution,
the conjugate base is added in a salt form (e.g..
sodium acetate NaCH,COO)
Buffers work because the conjugate acid-base pair
work together to neutralize the addition of Hor
OH ions. Thus, for example, it H ions are
added to the acetate buffer described above, they
will be largely removed from solution by the
reaction of H with the conjugate base:
H+CH₂COO-CH₂COOH
Similarly, any added OH ions will be neutralized
by a reaction with the conjugate acid
OH+CH₂COOH-CH₂COO + H₂O.
This butter system is described by the Henderson-
Hasselbalch equation
pH pK, +log
M
jugate base
conjugate acid
Part A
A beaker with 125 ml. of an acetic acid buffer with a pH of 5.000 is sitting on a benchtop. The total molarity of
acid and conjugate base in this buffer is 0.100 M. A student adds 9.00 mL of a 0310 M HCT solution to the
beaker. How much will the pH change? The pK, of acetic acid is 4.740.
Express your answer numerically to two decimal places. Use a minus (-) sign if the pit has
decreased.
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Transcribed Image Text:Learning Goal: To understand how buffers use reserves of conjugate acid and conjugate base to counteract the effects of acid or base addition on pH. A buffer is a mixture of a conjugate acid-base pair In other words, it is a solution that contains a weak acid and its conjugate base, or a weak base and its conjugate acid. For example, an acetic acid buffer consists of acetic acid, CH₂COOH, and its i conjugate base, the acetate ion CH, COO Because ions cannot simply be added to a solution, the conjugate base is added in a salt form (e.g.. sodium acetate NaCH,COO) Buffers work because the conjugate acid-base pair work together to neutralize the addition of Hor OH ions. Thus, for example, it H ions are added to the acetate buffer described above, they will be largely removed from solution by the reaction of H with the conjugate base: H+CH₂COO-CH₂COOH Similarly, any added OH ions will be neutralized by a reaction with the conjugate acid OH+CH₂COOH-CH₂COO + H₂O. This butter system is described by the Henderson- Hasselbalch equation pH pK, +log M jugate base conjugate acid Part A A beaker with 125 ml. of an acetic acid buffer with a pH of 5.000 is sitting on a benchtop. The total molarity of acid and conjugate base in this buffer is 0.100 M. A student adds 9.00 mL of a 0310 M HCT solution to the beaker. How much will the pH change? The pK, of acetic acid is 4.740. Express your answer numerically to two decimal places. Use a minus (-) sign if the pit has decreased. View Available Hint(s) Apl Submit Provide Feedback 15] ΑΣΦΑ ? Next >
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