On this educational page, we are examining whether the pairs of molecular structures shown are constitutional isomers, enantiomers, diastereomers, or identical. The various structural pairs are showcased from (a) to (h).### Pair a)- **Left Structure**: Bicyclic compound with chlorine (Cl) and bromine (Br) substituents; Cl and Br are on adjacent carbons.- **Right Structure**: Similar bicyclic structure; however, the positions of Cl and Br are interchanged compared to the left structure.### Pair b)- **Left Structure**: Cyclohexene with an NH₂ group attached to the first carbon.- **Right Structure**: Cyclohexene with an NH₂ group attached to an adjacent carbon in a different orientation.### Pair c)- **Left Structure**: Cyclohexane with Cl and OH groups on adjacent carbons in a trans orientation.- **Right Structure**: Cyclohexane with Cl and OH on adjacent carbons in a cis orientation.### Pair d)- **Left Structure**: Three-membered ring with an oxygen atom and two substituents pointing out.- **Right Structure**: Similar three-membered ring but with substituents oriented differently.### Pair e)- **Left Structure**: Linear open chain compound with a double bond.- **Right Structure**: Similar structure with a different double bond position.### Pair f)- **Left Structure**: Linear open chain compound with a double bond.- **Right Structure**: Cycloalkene, forming a five-membered ring with a double bond.### Pair g)- **Left Structure**: Bicyclic compound with additional substituents.- **Right Structure**: Similar bicyclic framework, differing slightly in substituent positioning.### Pair h)- **Left Structure**: V-shaped molecule with Br and Cl on adjacent carbons.- **Right Structure**: Same molecular framework with inverted Br and Cl positions compared to the left structure.Each set of structures provides an opportunity to discuss stereochemistry, functional groups, and molecular symmetry.

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Answered: а) b) NH2 and -CI and Br Br NH2 c) ОН…

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а) b) NH2 and -CI and Br Br NH2 c) ОН ОН d) and and

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10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Quantum Mechanical Treatment of the Valence Bond Theory

Quantum mechanical treatment of valence bond theory refers to the relationship established between the quantum mechanical theory and the valence bond theory to describe the chemical bonding in a particular molecule.

Question

On this educational page, we are examining whether the pairs of molecular structures shown are constitutional isomers, enantiomers, diastereomers, or identical. The various structural pairs are showcased from (a) to (h).

### Pair a)
- **Left Structure**: Bicyclic compound with chlorine (Cl) and bromine (Br) substituents; Cl and Br are on adjacent carbons.
- **Right Structure**: Similar bicyclic structure; however, the positions of Cl and Br are interchanged compared to the left structure.

### Pair b)
- **Left Structure**: Cyclohexene with an NH₂ group attached to the first carbon.
- **Right Structure**: Cyclohexene with an NH₂ group attached to an adjacent carbon in a different orientation.

### Pair c)
- **Left Structure**: Cyclohexane with Cl and OH groups on adjacent carbons in a trans orientation.
- **Right Structure**: Cyclohexane with Cl and OH on adjacent carbons in a cis orientation.

### Pair d)
- **Left Structure**: Three-membered ring with an oxygen atom and two substituents pointing out.
- **Right Structure**: Similar three-membered ring but with substituents oriented differently.

### Pair e)
- **Left Structure**: Linear open chain compound with a double bond.
- **Right Structure**: Similar structure with a different double bond position.

### Pair f)
- **Left Structure**: Linear open chain compound with a double bond.
- **Right Structure**: Cycloalkene, forming a five-membered ring with a double bond.

### Pair g)
- **Left Structure**: Bicyclic compound with additional substituents.
- **Right Structure**: Similar bicyclic framework, differing slightly in substituent positioning.

### Pair h)
- **Left Structure**: V-shaped molecule with Br and Cl on adjacent carbons.
- **Right Structure**: Same molecular framework with inverted Br and Cl positions compared to the left structure.

Each set of structures provides an opportunity to discuss stereochemistry, functional groups, and molecular symmetry.

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