(a) (b) (c) R HO on CH,OH CO₂H CH₂ CH₂ # CI CH₂ A. Constitutional isomers B. Enantiomers C. Diastereomers D. Identical compounds, or E None of the above CO₂H F CH₂ CH, CH -H # CE Answer: Answer Answer:

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**18. Determine whether the two structures in each of the following pairs represent:**

A. Constitutional isomers  
B. Enantiomers  
C. Diastereomers  
D. Identical compounds, or  
E. None of the above  

**(a)**  
- Structure 1: Ethanol with attachments at two carbons and OH groups on each.
- Structure 2: Propanol with OH groups on two carbons.  
Answer: _______

**(b)**  
- Structure 1: Chain structure with Br, OH, CH3, H, and a central carbon chain.
- Structure 2: Chain structure with Br, CH3, H, and OH attached differently compared to Structure 1.  
Answer: _______

**(c)**  
- Structure 1: Cyclohexane ring with CH3 substituents, one equatorial and one axial.
- Structure 2: Cyclohexane ring with both CH3 substituents equatorial.  
Answer: _______

**(d)**  
- Structure 1: Cyclopentane ring with one CH3 and one ethyl group.
- Structure 2: Cyclopentane ring with different positions for CH3 and ethyl group.  
Answer: _______

**(e)**  
- Structure 1: Cyclohexane ring in chair conformation with CH3 groups on alternate carbons.
- Structure 2: Cyclohexane ring in a different chair conformation with alternate substituent positions.  
Answer: _______

**Explanation:**  
Each pair represents either different structural isomers, stereoisomers, or identical molecules. The task is to identify which type of isomer each pair of structures represents.
Transcribed Image Text:**18. Determine whether the two structures in each of the following pairs represent:** A. Constitutional isomers B. Enantiomers C. Diastereomers D. Identical compounds, or E. None of the above **(a)** - Structure 1: Ethanol with attachments at two carbons and OH groups on each. - Structure 2: Propanol with OH groups on two carbons. Answer: _______ **(b)** - Structure 1: Chain structure with Br, OH, CH3, H, and a central carbon chain. - Structure 2: Chain structure with Br, CH3, H, and OH attached differently compared to Structure 1. Answer: _______ **(c)** - Structure 1: Cyclohexane ring with CH3 substituents, one equatorial and one axial. - Structure 2: Cyclohexane ring with both CH3 substituents equatorial. Answer: _______ **(d)** - Structure 1: Cyclopentane ring with one CH3 and one ethyl group. - Structure 2: Cyclopentane ring with different positions for CH3 and ethyl group. Answer: _______ **(e)** - Structure 1: Cyclohexane ring in chair conformation with CH3 groups on alternate carbons. - Structure 2: Cyclohexane ring in a different chair conformation with alternate substituent positions. Answer: _______ **Explanation:** Each pair represents either different structural isomers, stereoisomers, or identical molecules. The task is to identify which type of isomer each pair of structures represents.
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