A A strip of magnesium metal having a mass of 1.22 g dissolves in 100.0 mL of 6.02 M HCI, which has a density of 1.10 g/mL. The hydrochloric acid is initially at 23.0°C, and the resulting solution reaches a final temperature of 45.5°C. The heat capacity of the calorimeter in which the reaction occurs is 562 J/°C. Calculate AH (in kJ/mol) for the reaction under the conditions of the experiment, assuming the specific heat of the final solution is the same as that for water, 4.184 J/g°C. (Report numerical answer 4 significant figures) Mg(s) + 2HCI(aq) -> MgCl2(aq)+ H2(g)
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
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![A
A strip of magnesium metal having a mass of 1.22 g dissolves in 100.0 mL of 6.02 M HCI, which has a density of
1.10 g/mL. The hydrochloric acid is initially at 23.0°C, and the resulting solution reaches a final temperature
of 45.5°C. The heat capacity of the calorimeter in which the reaction occurs is 562 J/"C. Calculate AH (in kJ/mol)
for the reaction under the conditions of the experiment, assuming the specific heat of the final solution is the
same as that for water, 4.184 J/g°C. (Report numerical answer 4 significant figures)
Mg(s) + 2HC((aq) -> MgCl2(aq)+ H2(9)
В
From the following enthalpies of reaction,
4HCI(g) + 02(g) -> 2H20) + 2C12(g)
AH = -202.4 kJ/mol rxn
1/2 H2(g) + 1/2 F2(g) -> HF
AH = -600.0 kJ/mol rxn
%3D
H2(g) + 1/2 02(g) -> H201)
AH = -285.8 kJ/mol rxn
find AHrxn (in kJ/mol) for 2HCI(g) + F2(g) > 2HF) + Cl2(9). (Report numerical answer in 4 significant figures)
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