A 60.0 mL solution of 0.184 M sulfurous acid (H₂SO3) is titrated with 0.184 M NaOH. The pK₂ values of sulfurous acid are 1.857 (pKal) and 7.172 (pK a2). Calculate the pH at the first equivalence point. pH = 7.00 Calculate the pH at the second equivalence point.
A 60.0 mL solution of 0.184 M sulfurous acid (H₂SO3) is titrated with 0.184 M NaOH. The pK₂ values of sulfurous acid are 1.857 (pKal) and 7.172 (pK a2). Calculate the pH at the first equivalence point. pH = 7.00 Calculate the pH at the second equivalence point.
General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Chapter16: Acid-base Equilibria
Section: Chapter Questions
Problem 16.141QP: Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid,...
Related questions
Question

Transcribed Image Text:A 60.0 mL solution of 0.184 M sulfurous acid (H₂SO3) is titrated with 0.184 M NaOH. The pK a values of sulfurous acid are
1.857 (pKal) and 7.172 (pK a2).
Calculate the pH at the first equivalence point.
pH =
7.00
Calculate the pH at the second equivalence point.
pH =
10.25
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Step 1: Introduce the problem
VIEWStep 2: Calculate pH for the first equivalence point
VIEWStep 3: Calculate number of moles of (SO3)2-
VIEWStep 4: Calculate volume of NaOH
VIEWStep 5: Calculate concentration of (SO3)2- at the second equivalence point
VIEWStep 6: Calculate Kb value and write the expression for equilibrium constant
VIEWStep 7: Calculate concentration of [OH-]
VIEWStep 8: Calculate pH of the second equivalence point
VIEWSolution
VIEWTrending now
This is a popular solution!
Step by step
Solved in 9 steps with 25 images

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning

General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning