A 60.0 mL solution of 0.184 M sulfurous acid (H₂SO3) is titrated with 0.184 M NaOH. The pK₂ values of sulfurous acid are 1.857 (pKal) and 7.172 (pK a2). Calculate the pH at the first equivalence point. pH = 7.00 Calculate the pH at the second equivalence point.
A 60.0 mL solution of 0.184 M sulfurous acid (H₂SO3) is titrated with 0.184 M NaOH. The pK₂ values of sulfurous acid are 1.857 (pKal) and 7.172 (pK a2). Calculate the pH at the first equivalence point. pH = 7.00 Calculate the pH at the second equivalence point.
General Chemistry - Standalone book (MindTap Course List)
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Chapter16: Acid-base Equilibria
Section: Chapter Questions
Problem 16.141QP: Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid,...
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Step 1: Introduce the problem
VIEWStep 2: Calculate pH for the first equivalence point
VIEWStep 3: Calculate number of moles of (SO3)2-
VIEWStep 4: Calculate volume of NaOH
VIEWStep 5: Calculate concentration of (SO3)2- at the second equivalence point
VIEWStep 6: Calculate Kb value and write the expression for equilibrium constant
VIEWStep 7: Calculate concentration of [OH-]
VIEWStep 8: Calculate pH of the second equivalence point
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