A 400 MHz 'H NMR spectrum of a mixture of common organic solvents consisting of benzene (C6H6) 8 7.37; diethyl ether (C4H100) 8 3.49 and 8 1.22; and dichloromethane (CH2C12) 8 5.30 is given below. Estimate the relative proportions (mole %) of the 3 components from the integrals in the spectrum. CH3 - CH2-0-CH2-CH3 CI--CH2-CI benzene diethyl ether dichloromethane 'H NMR Spectrum (400 MHz, CDCI3 solution) 3.5 3.4 ppm 1.3 1.2 ppm 7 3 2 1 ppm Compound Mole % benzene diethyl ether dichoromethane

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Chapter1: Chemical Foundations
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A 400 MHz 'H NMR spectrum of a mixture of common organic solvents consisting of
benzene (C,H6) 8 7.37; diethyl ether (C4H100) 8 3.49 and 8 1.22; and dichloromethane
(CH2Cl2) 8 5.30 is given below. Estimate the relative proportions (mole %) of the
3 components from the integrals in the spectrum.
CH3 - CH2-0-CH2-CH3
CI-CH2-CI
benzene
diethyl ether
dichloromethane
'H NMR Spectrum
(400 MHz, CDCI; solution)
lle
3.5
3.4 ppm
1.3
1.2
ppm
8
7
4
3
1
ppm
Compound
Mole %
benzene
diethyl ether
dichoromethane
Transcribed Image Text:A 400 MHz 'H NMR spectrum of a mixture of common organic solvents consisting of benzene (C,H6) 8 7.37; diethyl ether (C4H100) 8 3.49 and 8 1.22; and dichloromethane (CH2Cl2) 8 5.30 is given below. Estimate the relative proportions (mole %) of the 3 components from the integrals in the spectrum. CH3 - CH2-0-CH2-CH3 CI-CH2-CI benzene diethyl ether dichloromethane 'H NMR Spectrum (400 MHz, CDCI; solution) lle 3.5 3.4 ppm 1.3 1.2 ppm 8 7 4 3 1 ppm Compound Mole % benzene diethyl ether dichoromethane
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