A 100 kmol/h stream that is 97 mole% carbon tetrachloride (CCI14) and 3% carbon disulphide (CS2) is to be recovered from the bottom of a distillation column. The feed to the column is 16 mole% CS2 and 84% CC14, and 2.5% of the CC14 entering the column leaves in the overhead (top of column). a) Draw and label a flowchart of the process and do the degree-of-freedom analysis. b) Calculate the mass and mole fractions of CC14 in the overhead stream and determine the molar flow rates of CCl4 and CS2 (kmol/h) in the overhead and feed streams

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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4. A 100 kmol/h stream that is 97 mole% carbon tetrachloride (CC14) and 3% carbon
disulphide (CS2) is to be recovered from the bottom of a distillation column. The feed
to the column is 16 mole% CS2 and 84% CC14, and 2.5% of the CCI4 entering the
column leaves in the overhead
(top of column).
a) Draw and label a flowchart of the process and do the degree-of-freedom analysis.
b) Calculate the mass and mole fractions of CC14 in the overhead stream and
determine the molar flow rates of CC14 and CS2 (kmol/h) in the overhead and feed
streams
Transcribed Image Text:4. A 100 kmol/h stream that is 97 mole% carbon tetrachloride (CC14) and 3% carbon disulphide (CS2) is to be recovered from the bottom of a distillation column. The feed to the column is 16 mole% CS2 and 84% CC14, and 2.5% of the CCI4 entering the column leaves in the overhead (top of column). a) Draw and label a flowchart of the process and do the degree-of-freedom analysis. b) Calculate the mass and mole fractions of CC14 in the overhead stream and determine the molar flow rates of CC14 and CS2 (kmol/h) in the overhead and feed streams
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