A 10.0-ml sample of aqueous NaOCI is treated with excess KI in an acidic solution. The quantity of iodine that is liberated is such that 28.02 mL of 0.0250 M Na2S₂O, solution must be added to cause the disappearance of the dark blue color due to the starch indicator. What is the molarity of the solution of NaOCI?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Redo the third problem of the Prelaboratory Assignment, substituting NaIO3 (sodium iodate) for NaOCl. The new reaction yields I2 as the only product containing a halogen.

3.
A 10.0-mL sample of aqueous NaOCI is treated with excess KI in an acidic solution. The quantity
of iodine that is liberated is such that 28.02 mL of 0.0250 M Na₂S₂O3 solution must be added to
cause the disappearance of the dark blue color due to the starch indicator. What is the molarity of
the solution of NaOCI?
# of moles of Na2S203 = M*V= 0.0250 M * 28.02mL = 0.7005mmol
2. According to the balanced equation
2 moles of $203 2- reacts with 1 mole of CIO-
so 0.7005mmol of $203 2- reacts with 0.7005 mmol * 1/2 = 0.35025 mmol of CIO-
# of moles of NaOCI= 0.35025 mmol
volume = 10ml
Molarity of NaOCI=0.35025 mmol/ 10.0ml = 0.0350 M
Transcribed Image Text:3. A 10.0-mL sample of aqueous NaOCI is treated with excess KI in an acidic solution. The quantity of iodine that is liberated is such that 28.02 mL of 0.0250 M Na₂S₂O3 solution must be added to cause the disappearance of the dark blue color due to the starch indicator. What is the molarity of the solution of NaOCI? # of moles of Na2S203 = M*V= 0.0250 M * 28.02mL = 0.7005mmol 2. According to the balanced equation 2 moles of $203 2- reacts with 1 mole of CIO- so 0.7005mmol of $203 2- reacts with 0.7005 mmol * 1/2 = 0.35025 mmol of CIO- # of moles of NaOCI= 0.35025 mmol volume = 10ml Molarity of NaOCI=0.35025 mmol/ 10.0ml = 0.0350 M
The Strength of a Laundry Bleach
Prelaboratory Assignment
Write the balanced equations for the following oxidation-reduction reactions that you will
encounter in this experiment:
The reduction of CIO by I in acidic solution
1.
2.
a.
C1012H₂0+21Iz+CI+H₂O
b.
The reduction of I₂ by S₂O3 in acidic solution
2-
1₂+ 25 ₂0²² → 21+ Sad
What conversion factor will enable you to calculate the number of moles of ClO ions from the
number of moles of S₂O3 ions used in the titration?
2-
2 moles of $₂03 = 1 mole of
CIÓ
Transcribed Image Text:The Strength of a Laundry Bleach Prelaboratory Assignment Write the balanced equations for the following oxidation-reduction reactions that you will encounter in this experiment: The reduction of CIO by I in acidic solution 1. 2. a. C1012H₂0+21Iz+CI+H₂O b. The reduction of I₂ by S₂O3 in acidic solution 2- 1₂+ 25 ₂0²² → 21+ Sad What conversion factor will enable you to calculate the number of moles of ClO ions from the number of moles of S₂O3 ions used in the titration? 2- 2 moles of $₂03 = 1 mole of CIÓ
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps

Blurred answer
Follow-up Questions
Read through expert solutions to related follow-up questions below.
Follow-up Question

Redo the third problem of the Prelaboratory Assignment, substituting NaIO3 (sodium iodate) for NaOCl. The new reaction yields I2 as the only product containing a halogen?

Solution
Bartleby Expert
SEE SOLUTION
Knowledge Booster
Redox Titrations
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY