A 1.509-g sample of a Pb/Cd alloy was dissolved in acid and diluted to exactly 250.0 mL in a volumetric flask. A 50.00-mL aliquot of the diluted solution was brought to a pH of 10.00 with a NH4+/NH3 buffer; the subsequent titration involved both cations and required 28.89 mL of 0.06950 M EDTA. A second 50.00-mL aliquot was brought to a pH of 10.00 with an HCN/NaCN buffer, which also served to mask the Cd2+; 11.56 mL of the EDTA solution were needed to titrate the Pb2+. Calculate % Cd
A 1.509-g sample of a Pb/Cd alloy was dissolved in acid and diluted to exactly 250.0 mL in a volumetric flask. A 50.00-mL aliquot of the diluted solution was brought to a pH of 10.00 with a NH4+/NH3 buffer; the subsequent titration involved both cations and required 28.89 mL of 0.06950 M EDTA. A second 50.00-mL aliquot was brought to a pH of 10.00 with an HCN/NaCN buffer, which also served to mask the Cd2+; 11.56 mL of the EDTA solution were needed to titrate the Pb2+. Calculate % Cd
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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A 1.509-g sample of a Pb/Cd alloy was dissolved in acid and diluted to exactly 250.0 mL in a volumetric flask. A 50.00-mL aliquot of the diluted solution was brought to a pH of 10.00 with a NH4+/NH3 buffer; the subsequent titration involved both cations and required 28.89 mL of 0.06950 M EDTA. A second 50.00-mL aliquot was brought to a pH of 10.00 with an HCN/NaCN buffer, which also served to mask the Cd2+; 11.56 mL of the EDTA solution were needed to titrate the Pb2+. Calculate % Cd in thesample. Express your answer in 2 decimal places.
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