A 1.00-g sample of hexane, C6H14, undergoes complete combustion with excess O2 in a bomb calorimeter. The temperature of the 1500. g of water surrounding the bomb rises from 22.64°C to 29.30°C. The heat capacity of the calorimeter is 4.04 kJ/°C. What is change in internal energy for the reaction in kJ/mol of C6H14. The specific heat of water is 4.184 J/g•°C.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
A 1.00-g sample of hexane, C6H14, undergoes complete combustion with excess O2 in a bomb calorimeter. The temperature of the 1500. g of water surrounding the bomb rises from 22.64°C to 29.30°C. The heat capacity of the calorimeter is 4.04 kJ/°C. What is change in internal energy for the reaction in kJ/mol of C6H14. The specific heat of water is 4.184 J/g•°C.
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