A 1 cm diameter spherical pellet of a strongly basic oxide is held at the center of a closed vessel of 5-liter volume. Initially the vessel is evacuated and then filled with an equimolar mixture of H₂S and N₂ at 25 °C and 1 atm total pressure. As the molecules of H₂S reach the surface of the pellet, they get absorbed instantaneously so that the concentration of H₂S at the surface remains zero at all time. Diffusion of H₂S occurs through a stagnant film of estimated thickness of 4 mm surrounding the pellet. The bulk of the gas may be assumed to have a uniform composition at any time. Calculate the time of absorption of 95% of H₂S in nitrogen is 1.73x105 m²/s at this temperature and 1 atm pressure.

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Chapter1: Chemical Foundations
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A 1 cm diameter spherical pellet of a strongly basic oxide is held at the center of a closed
vessel of 5-liter volume. Initially the vessel is evacuated and then filled with an equimolar
mixture of H₂S and N₂ at 25 °C and 1 atm total pressure. As the molecules of H₂S reach the
surface of the pellet, they get absorbed instantaneously so that the concentration of H₂S at the
surface remains zero at all time. Diffusion of H₂S occurs through a stagnant film of estimated
thickness of 4 mm surrounding the pellet. The bulk of the gas may be assumed to have a
uniform composition at any time. Calculate the time of absorption of 95% of H₂S in nitrogen
is 1.73x10 m²/s at this temperature and 1 atm pressure.
Closed vessel, volume = 5 litres
Mixture of H₂S (4)
and N₂ (B)
H₂S diffuses through N₂
H₂S.
Absorbent sphere
Total pressure,
P=0.5+PAD
Gas-film of
thickness,
8=4 mm
Transcribed Image Text:A 1 cm diameter spherical pellet of a strongly basic oxide is held at the center of a closed vessel of 5-liter volume. Initially the vessel is evacuated and then filled with an equimolar mixture of H₂S and N₂ at 25 °C and 1 atm total pressure. As the molecules of H₂S reach the surface of the pellet, they get absorbed instantaneously so that the concentration of H₂S at the surface remains zero at all time. Diffusion of H₂S occurs through a stagnant film of estimated thickness of 4 mm surrounding the pellet. The bulk of the gas may be assumed to have a uniform composition at any time. Calculate the time of absorption of 95% of H₂S in nitrogen is 1.73x10 m²/s at this temperature and 1 atm pressure. Closed vessel, volume = 5 litres Mixture of H₂S (4) and N₂ (B) H₂S diffuses through N₂ H₂S. Absorbent sphere Total pressure, P=0.5+PAD Gas-film of thickness, 8=4 mm
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