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9. The carbonyl in acetophenone, below at left, is a withdrawing group. Draw its resonance structures (fill in π bonds and charges) to show which ring carbons are made more electrophilic (that is, electron-poor) by the withdrawing group. 8--8-8-8 10. The methoxy group in anisole, below at left, is a donating group. Draw its resonance structures (fill in π bonds and charges) to show which ring carbons are made more nucleophilic (that is, electron-rich) by the donating group. 8-8-8-8 11. Draw the first nitration product when acetophenone (above) is treated with nitric acid and sulfuric acid. Then, do the same with anisole (also above). Which reaction is faster?

9. The carbonyl in acetophenone, below at left, is a withdrawing group. Draw its resonance structures (fill in π bonds and charges) to show which ring carbons are made more electrophilic (that is, electron-poor) by the withdrawing group. 8--8-8-8 10. The methoxy group in anisole, below at left, is a donating group. Draw its resonance structures (fill in π bonds and charges) to show which ring carbons are made more nucleophilic (that is, electron-rich) by the donating group. 8-8-8-8 11. Draw the first nitration product when acetophenone (above) is treated with nitric acid and sulfuric acid. Then, do the same with anisole (also above). Which reaction is faster?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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9. The carbonyl in acetophenone, below at left, is a withdrawing group. Draw its resonance structures (fill in π bonds and charges) to show which ring carbons are made more electrophilic (that is, electron-poor) by the withdrawing group. 8--8-8-8 10. The methoxy group in anisole, below at left, is a donating group. Draw its resonance structures (fill in π bonds and charges) to show which ring carbons are made more nucleophilic (that is, electron-rich) by the donating group. 8-8-8-8 11. Draw the first nitration product when acetophenone (above) is treated with nitric acid and sulfuric acid. Then, do the same with anisole (also above). Which reaction is faster?
Transcribed Image Text:9. The carbonyl in acetophenone, below at left, is a withdrawing group. Draw its resonance structures (fill in π bonds and charges) to show which ring carbons are made more electrophilic (that is, electron-poor) by the withdrawing group. 8--8-8-8 10. The methoxy group in anisole, below at left, is a donating group. Draw its resonance structures (fill in π bonds and charges) to show which ring carbons are made more nucleophilic (that is, electron-rich) by the donating group. 8-8-8-8 11. Draw the first nitration product when acetophenone (above) is treated with nitric acid and sulfuric acid. Then, do the same with anisole (also above). Which reaction is faster?
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