9. a) Draw the splitting energy diagram for the ground state of each of the three octahedral complex ions, Ni(en)3²+ (aq), Ni(NH3)6²+ (aq), and Ni(H₂O)²+(aq). In the diagrams, show how the d-orbitals compare energetically between these three Ni²+ complex ions. (Hint: Think about the relative ligand strengths.)

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9. a) Draw the splitting energy diagram for the ground state of each of the three octahedral
complex ions, Ni(en)32+ (aq), Ni(NH3)6²+ (aq), and Ni(H₂O)6²+ (aq). In the diagrams, show
how the d-orbitals compare energetically between these three Ni²+ complex ions. (Hint:
Think about the relative ligand strengths.)
b) Does Ni²+ form high and low spin complexes? If so, designate which ones from part a
are high spin and which are low spin. If Ni²+ does not form high and low spin complexes,
explain why not.
Transcribed Image Text:9. a) Draw the splitting energy diagram for the ground state of each of the three octahedral complex ions, Ni(en)32+ (aq), Ni(NH3)6²+ (aq), and Ni(H₂O)6²+ (aq). In the diagrams, show how the d-orbitals compare energetically between these three Ni²+ complex ions. (Hint: Think about the relative ligand strengths.) b) Does Ni²+ form high and low spin complexes? If so, designate which ones from part a are high spin and which are low spin. If Ni²+ does not form high and low spin complexes, explain why not.
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