9-2. Consider this thermochem ical equation: 4 PCl() → Pa(s) + 6 Ch(g) AH° = +1278.8 kJ If the chlorine gas is collected at STP, then what volume of chlorine is produced when 68 joules are absorbed in the reaction?

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**Thermochemical Equation Analysis**

**Question 9-2:**

Consider the following thermochemical equation:

\[ 4 \, \text{PCl}_3(l) \rightarrow \text{P}_4(s) + 6 \, \text{Cl}_2(g) \]

\[ \Delta H^\circ = +1278.8 \, \text{kJ} \]

**Problem Statement:**

If the chlorine gas is collected at Standard Temperature and Pressure (STP), determine the volume of chlorine gas produced when 68 joules are absorbed in the reaction.

**Explanation:**

This is a thermochemical equation describing the reaction where liquid phosphorus trichloride (\(\text{PCl}_3\)) is converted into solid phosphorus (\(\text{P}_4\)) and gaseous chlorine (\(\text{Cl}_2\)). The enthalpy change (\(\Delta H^\circ\)) for this reaction is \(+1278.8 \, \text{kJ}\), indicating that the reaction absorbs energy.

**Objective:**

To find out how much chlorine gas (\(\text{Cl}_2\)) is generated when 68 joules of energy are absorbed at STP conditions. 

**Approach:**

- Use the given enthalpy change to determine the proportion of chlorine gas produced with 68 joules of absorbed energy.
- Apply gas laws to calculate the volume of gas produced under STP conditions, knowing that one mole of gas occupies 22.4 liters at STP.
Transcribed Image Text:**Thermochemical Equation Analysis** **Question 9-2:** Consider the following thermochemical equation: \[ 4 \, \text{PCl}_3(l) \rightarrow \text{P}_4(s) + 6 \, \text{Cl}_2(g) \] \[ \Delta H^\circ = +1278.8 \, \text{kJ} \] **Problem Statement:** If the chlorine gas is collected at Standard Temperature and Pressure (STP), determine the volume of chlorine gas produced when 68 joules are absorbed in the reaction. **Explanation:** This is a thermochemical equation describing the reaction where liquid phosphorus trichloride (\(\text{PCl}_3\)) is converted into solid phosphorus (\(\text{P}_4\)) and gaseous chlorine (\(\text{Cl}_2\)). The enthalpy change (\(\Delta H^\circ\)) for this reaction is \(+1278.8 \, \text{kJ}\), indicating that the reaction absorbs energy. **Objective:** To find out how much chlorine gas (\(\text{Cl}_2\)) is generated when 68 joules of energy are absorbed at STP conditions. **Approach:** - Use the given enthalpy change to determine the proportion of chlorine gas produced with 68 joules of absorbed energy. - Apply gas laws to calculate the volume of gas produced under STP conditions, knowing that one mole of gas occupies 22.4 liters at STP.
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