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8. For each of the following alkenes, assign the configuration of the double bond as either E or Z (a) (b) (c) (d)

8. For each of the following alkenes, assign the configuration of the double bond as either E or Z (a) (b) (c) (d)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Question 8:** For each of the following alkenes, assign the configuration of the double bond as either E or Z. **(a)** The structure consists of a carbon chain with a double bond in the middle. Each side of the double bond has two hydrocarbon branches. **(b)** The structure features a cyclohexane ring with a double bond extending to an alkyl chain and an alkyl group connected to a five-membered ring. **(c)** The structure has a double bond with a fluorine atom on one side and an ether and tert-butyl group on the other side. **(d)** The structure includes a double bond with a chlorine atom and an ethyl group on one end, and an isopropyl group on the other end. **Explanation:** When determining E/Z configuration: - E (Entgegen) configuration is when the highest priority substituents on each carbon of the double bond are on opposite sides. - Z (Zusammen) configuration is when the highest priority substituents on each carbon of the double bond are on the same side. Priority is determined based on atomic numbers; higher atomic numbers have higher priority.
Transcribed Image Text:**Question 8:** For each of the following alkenes, assign the configuration of the double bond as either E or Z. **(a)** The structure consists of a carbon chain with a double bond in the middle. Each side of the double bond has two hydrocarbon branches. **(b)** The structure features a cyclohexane ring with a double bond extending to an alkyl chain and an alkyl group connected to a five-membered ring. **(c)** The structure has a double bond with a fluorine atom on one side and an ether and tert-butyl group on the other side. **(d)** The structure includes a double bond with a chlorine atom and an ethyl group on one end, and an isopropyl group on the other end. **Explanation:** When determining E/Z configuration: - E (Entgegen) configuration is when the highest priority substituents on each carbon of the double bond are on opposite sides. - Z (Zusammen) configuration is when the highest priority substituents on each carbon of the double bond are on the same side. Priority is determined based on atomic numbers; higher atomic numbers have higher priority.
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