8. Assign an inner-sphere or an outer-sphere mechanism for the following reactions, and draw out the details of the reaction sequence: 3+ (a) Co(NH;),N + [Fe(CN),OH,]³- The Co reactant is substitution inert, while the Fe" reactant is substitution labile. The products are Co2+ (aq), which is substitution labile, and 2- Fe(CN),N N which is substitution inert. (b) [Co(NH;),]³+ + [Fe(CN),OH¿]³ The hexaammine of cobalt is substitution inert and the Fell reactant is substitution labile. The products are Co2+ (aq) and [Fe(CN),OH¿]².
8. Assign an inner-sphere or an outer-sphere mechanism for the following reactions, and draw out the details of the reaction sequence: 3+ (a) Co(NH;),N + [Fe(CN),OH,]³- The Co reactant is substitution inert, while the Fe" reactant is substitution labile. The products are Co2+ (aq), which is substitution labile, and 2- Fe(CN),N N which is substitution inert. (b) [Co(NH;),]³+ + [Fe(CN),OH¿]³ The hexaammine of cobalt is substitution inert and the Fell reactant is substitution labile. The products are Co2+ (aq) and [Fe(CN),OH¿]².
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![8. Assign an inner-sphere or an outer-sphere mechanism for the following reactions, and draw
out the details of the reaction sequence:
3+
(a)
Co(NH3);N
N
+
[Fe(CN),OH,]*-
The Co reactant is substitution inert, while the Fel" reactant is substitution labile. The products
are Co2+ (aq), which is substitution labile, and
2-
Fe(CN),N
N
which is substitution inert.
(b) [Co(NH3),]³++ [Fe(CN),OH¿]³-
The hexaammine of cobalt is substitution inert and the Fe reactant is substitution labile.
The products are Co?+ (aq) and [Fe(CN),OH;]².](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbd4b1e20-3006-49de-af22-6e42322eca98%2F3a81b5ce-f917-459c-a139-ceaa4539001f%2F5m3wkvg_processed.png&w=3840&q=75)
Transcribed Image Text:8. Assign an inner-sphere or an outer-sphere mechanism for the following reactions, and draw
out the details of the reaction sequence:
3+
(a)
Co(NH3);N
N
+
[Fe(CN),OH,]*-
The Co reactant is substitution inert, while the Fel" reactant is substitution labile. The products
are Co2+ (aq), which is substitution labile, and
2-
Fe(CN),N
N
which is substitution inert.
(b) [Co(NH3),]³++ [Fe(CN),OH¿]³-
The hexaammine of cobalt is substitution inert and the Fe reactant is substitution labile.
The products are Co?+ (aq) and [Fe(CN),OH;]².
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