8. Assign an inner-sphere or an outer-sphere mechanism for the following reactions, and draw out the details of the reaction sequence: 3+ (a) Co(NH;),N + [Fe(CN),OH,]³- The Co reactant is substitution inert, while the Fe" reactant is substitution labile. The products are Co2+ (aq), which is substitution labile, and 2- Fe(CN),N N which is substitution inert. (b) [Co(NH;),]³+ + [Fe(CN),OH¿]³ The hexaammine of cobalt is substitution inert and the Fell reactant is substitution labile. The products are Co2+ (aq) and [Fe(CN),OH¿]².

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8. Assign an inner-sphere or an outer-sphere mechanism for the following reactions, and draw
out the details of the reaction sequence:
3+
(a)
Co(NH3);N
N
+
[Fe(CN),OH,]*-
The Co reactant is substitution inert, while the Fel" reactant is substitution labile. The products
are Co2+ (aq), which is substitution labile, and
2-
Fe(CN),N
N
which is substitution inert.
(b) [Co(NH3),]³++ [Fe(CN),OH¿]³-
The hexaammine of cobalt is substitution inert and the Fe reactant is substitution labile.
The products are Co?+ (aq) and [Fe(CN),OH;]².
Transcribed Image Text:8. Assign an inner-sphere or an outer-sphere mechanism for the following reactions, and draw out the details of the reaction sequence: 3+ (a) Co(NH3);N N + [Fe(CN),OH,]*- The Co reactant is substitution inert, while the Fel" reactant is substitution labile. The products are Co2+ (aq), which is substitution labile, and 2- Fe(CN),N N which is substitution inert. (b) [Co(NH3),]³++ [Fe(CN),OH¿]³- The hexaammine of cobalt is substitution inert and the Fe reactant is substitution labile. The products are Co?+ (aq) and [Fe(CN),OH;]².
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