Rh(PPh3)3Cl] is a precatalyst that can be activated by dissociation of a phosphine ligand to form an active catalyst, B, which is used in the hydrogenation of alkenes. The active catalyst can then undergo oxidative addition in the presence of H2 to form complex C. Propene coordinates to C to form complex D, which then undergoes a 1,2- insertion step to form E. Reductive elimination of propane from E regenerates the active catalyst B.
Catalysis and Enzymatic Reactions
Catalysis is the kind of chemical reaction in which the rate (speed) of a reaction is enhanced by the catalyst which is not consumed during the process of reaction and afterward it is removed when the catalyst is not used to make up the impurity in the product. The enzymatic reaction is the reaction that is catalyzed via enzymes.
Lock And Key Model
The lock-and-key model is used to describe the catalytic enzyme activity, based on the interaction between enzyme and substrate. This model considers the lock as an enzyme and the key as a substrate to explain this model. The concept of how a unique distinct key only can have the access to open a particular lock resembles how the specific substrate can only fit into the particular active site of the enzyme. This is significant in understanding the intermolecular interaction between proteins and plays a vital role in drug interaction.
[Rh(PPh3)3Cl] is a precatalyst that can be activated by dissociation of a phosphine ligand to form an active catalyst, B, which is used in the hydrogenation of
Draw complexes B – E and hence provide a full catalytic cycle, including the activation step, for the hydrogenation of propene
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