8) Show detailed work for the Diels-Alder reaction below. To obtain full pass, you need to i) demonstrating drawings illustrating the additions and draw the final product in each scenario, ii) provide if the diene has cis or trans, 3) identify if dienophile is cis or trans, and show stereochemistry for the product upon addition. Note: Only 1 equivalence is present in each scenario for the reactants. (Pass/No Pass) b) c) d) G CH3 & - OOCH3 OOCH3 CH300 COCH 3

8) Show detailed work for the Diels-Alder reaction below. To obtain full pass, you need to i) demonstrating drawings illustrating the additions and draw the final product in each scenario, ii) provide if the diene has cis or trans, 3) identify if dienophile is cis or trans, and show stereochemistry for the product upon addition. Note: Only 1 equivalence is present in each scenario for the reactants. (Pass/No Pass) b) c) d) G CH3 & - OOCH3 OOCH3 CH300 COCH 3

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter8: Haloalkanes, Halogenation, And Radical Reactions

Section: Chapter Questions

Problem 8.21P

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to doinw 4. -> A) Which of the following is NOT a suitable diene for a Diels-Alder reaction? ultiple alkylation B) HBr CHEM 242 Activity 2.1-Conjugated-Systems D) 5. In the addition of HBr to 1,3-butadiene, one product is called the kinetic product and the other is called the thermodynamic product. doccriptors that apply to the kinetic product.
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(C) Provide the starting materials (diene and dienophile) necessary to form the ind product through a Diels-Alder reaction (beware of the stereochemical information). (a) (b) (c) (d) - Diene - Dienophile- Diene Dienophile - Diene + Dienophile- -Diene Dienophile- A Dor Br Br A ✓ CO₂Me CO₂Me A 4 A MeO CN
Cc.9.