8) A sample of 1 mol of perfect gas at 298 K and I bar with Cvm = 3/2 R and Cpm = 5/2 R is put through the following cycle: (a) constant-volume heating to twice its initial pressure, (b) reversible, adiabatic expansion back to its initial temperature, (c) reversible, isothermal compression back to 1 bar. Calculate q, w, AU, and AH for each step, as well as any necessary variables (e.g. V₁, T, etc.)
8) A sample of 1 mol of perfect gas at 298 K and I bar with Cvm = 3/2 R and Cpm = 5/2 R is put through the following cycle: (a) constant-volume heating to twice its initial pressure, (b) reversible, adiabatic expansion back to its initial temperature, (c) reversible, isothermal compression back to 1 bar. Calculate q, w, AU, and AH for each step, as well as any necessary variables (e.g. V₁, T, etc.)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Thermodynamic Cycle Problem:**
A sample of 1 mol of perfect gas at 298 K and 1 bar with \( C_{v,m} = \frac{3}{2} R \) and \( C_{p,m} = \frac{5}{2} R \) is put through the following cycle:
- (a) Constant-volume heating to twice its initial pressure.
- (b) Reversible, adiabatic expansion back to its initial temperature.
- (c) Reversible, isothermal compression back to 1 bar.
Calculate \( q \), \( w \), \( \Delta U \), and \( \Delta H \) for each step, as well as any necessary variables (e.g., \( V_i \), \( T_f \) etc.).
**Given:**
- \( n = 1 \) mol
- \( T = 298 \) K
- \( P = 1 \) bar
- \( C_{v,m} = \frac{3}{2} R \)
- \( C_{p,m} = \frac{5}{2} R \)
**Equations:**
- \( pV = nRT \)
- \( V = \frac{nRT}{P} \)
**Cycle Analysis:**
- Part (a):
- \(\omega = 0\)
- \( n = 1 \)
- \( T = 298 \) K
- \( C_{v,m} = \frac{3}{2} R \)
- \(\Delta P = 1 \) bar
- To be calculated:
- \( q = \)
- \( \Delta U = \)
- \( \Delta H = \)
- Part (b):
- To be completed.
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This transcription captures the problem setup, the given values, and the equations necessary for solving the thermodynamic cycle problem.
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