1) Consider a system consisting of 1.5 mol CO2 (g), initially at 15°C and 9.0 atm and confined to a cylinder of cross-section 100.0 cm2 , The sample is allowed to expand adiabatically against an external pressure of 1.5 atm until the piston has moved outwards through 15 cm. Assume that carbon dioxide may be considered a perfect gas with CV,m = 28.8 J K-l mol-1 , and calculate; (a) q, (b) w, (c) ∆U, (d) ∆T, (e) ∆S.

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1) Consider a system consisting of 1.5 mol CO2 (g), initially at 15°C and 9.0 atm and confined to a cylinder of cross-section 100.0 cm2 , The sample is allowed to expand adiabatically against an external pressure of 1.5 atm until the piston has moved outwards through 15 cm. Assume that carbon dioxide may be considered a perfect gas with CV,m = 28.8 J K-l mol-1 , and calculate;

(a) q,

(b) w,

(c) ∆U,

(d) ∆T,

(e) ∆S.

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