ConstantsIdeal gas constant:= 8.314 J K mol-= 0.083 dm bar K mol= 0.082 dm atm K molAvogadro's constant: NA = 6.022x1023 mol-!Boltzmann constant: k 1.38x1023 J KSpeed of light:c = 3 x 10% m sPlanck's constant:h = 6.626x1034 J s1 bar = 105 Pa1 atm = 101325 PaRelationsU = NKT²(n= + k In QS =%3DA = -kT In QG = -NkT In)R. 8) A certain photochemical process has fluorescence lifetime of tr=10-10 s and internal conversionrate constant of kie = 10" s . Assuming that the rate constants for the intersystem crossing andquenching are sufficiently small so that these processes can be neglected, calculatea)the rate constant for the deactivation of the excited state by fluorescence. ky=b)the fluorescence quantum yield.Workouts

Given: Life time, τf=10-10Internal conversion rate constant,kic=109 s-1 To find: a) kfb) ϕf

Answered: 8) A certain photochemical process has…

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