7.5 (a) Write equations to show how you expect compounds 7.24 to 7.28 to dissociate in aqueous solution. (b) Suggest how compound 7.29 will react with NaOH in aqueous solution. What salts would it be possible to isolate? (c) While it is convenient to draw the structures of compounds 7.24 to 7.28 as shown below, these suggest that the P and S atoms violate the octet rule. Redraw structures 7.24 and 7.25 so that the P atoms obey the octet rule. HO OH HO OH OH (7.24) (7.25) (7.26) OH H2N OH OH (7.27) (7.28) HO,C CO,H HO,C CO,H (7.29)

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Chapter1: Chemical Foundations
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7.5 (a) Write equations to show how you expect
compounds 7.24 to 7.28 to dissociate in aqueous
solution. (b) Suggest how compound 7.29 will
react with NaOH in aqueous solution. What salts
would it be possible to isolate? (c) While it is
convenient to draw the structures of compounds
7.24 to 7.28 as shown below, these suggest that
the P and S atoms violate the octet rule. Redraw
structures 7.24 and 7.25 so that the P atoms obey
the octet rule.
HO
HO
HO,
HO,
OH
(7.24)
(7.25)
(7.26)
OH
H;N
HO.
OH
(7.27)
(7.28)
HO,C
CO,H
HO,C
CO,H
(7.29)
Transcribed Image Text:7.5 (a) Write equations to show how you expect compounds 7.24 to 7.28 to dissociate in aqueous solution. (b) Suggest how compound 7.29 will react with NaOH in aqueous solution. What salts would it be possible to isolate? (c) While it is convenient to draw the structures of compounds 7.24 to 7.28 as shown below, these suggest that the P and S atoms violate the octet rule. Redraw structures 7.24 and 7.25 so that the P atoms obey the octet rule. HO HO HO, HO, OH (7.24) (7.25) (7.26) OH H;N HO. OH (7.27) (7.28) HO,C CO,H HO,C CO,H (7.29)
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