7. Propose a mechanism to account for the formation of products formed by decomposition of diazocyclodecane in the following reaction. N2 H. H H + + 18% 62% 14% 6% 8. Write a suitable mechanism for the following transformations. CHCI3 (i) Base CHCI2 H R (ii) cat. Rh2+ R N2 CHO hv, MeOH (ii) O: THF CO,Me N3 Heat (iv) NH2 Toluene hv, MeOH CO2M (v)

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Chapter1: Chemical Foundations
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7. Propose a mechanism to account for the formation of products formed by
decomposition of diazocyclodecane in the following reaction.
N2
H.
-N2
H.
H.
62%
14%
6%
18%
8. Write a suitable mechanism for the following transformations.
CHCI3
(i)
Base
CHCI2
(ii)
R.
cat. Rh2+
CHO
hv, MeOH
(iii)
O:
O.
THF
N2
CO,Me
N3
Heat
(iv)
NH2
Toluene
CO,Me
hv, MeOH
(v)
Transcribed Image Text:7. Propose a mechanism to account for the formation of products formed by decomposition of diazocyclodecane in the following reaction. N2 H. -N2 H. H. 62% 14% 6% 18% 8. Write a suitable mechanism for the following transformations. CHCI3 (i) Base CHCI2 (ii) R. cat. Rh2+ CHO hv, MeOH (iii) O: O. THF N2 CO,Me N3 Heat (iv) NH2 Toluene CO,Me hv, MeOH (v)
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