7. 13.74 The following data were collected for the reaction between hydrogen and nitric oxide at 700°C: 2H₂(g) + 2NO(g) →→2H₂O(g) + N₂(g) Experiment 1 2 3 [H₂] 0.010 0.0050 0.010 [NO] 0.025 0.025 0.0125 Initial Rate (M/s) 2.4 x 10-6 1.2 x 10-6 0.60 × 10-6 (a) Determine the order of the reaction. (b) Calcu- late the rate constant. (c) Suggest a plausible mech- anism that is consistent with the rate law. (Hint: Assume that the oxygen atom is the intermediate.)

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Chapter11: Chemical Kinetics
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7.
13.74 The following data were collected for the reaction
between hydrogen and nitric oxide at 700°C:
Experiment
1
2
3
2H₂(g) + 2NO(g) →→ 2H₂O(g) + N₂(8)
curied out at 430°C
[H₂]
0.010
0.0050
0.010
[NO]
0.025
0.025
0.0125
Initial Rate (M/s)
2.4 x 10-6
1.2 × 10-6
0.60 × 10-6
(a) Determine the order of the reaction. (b) Calcu-
late the rate constant. (c) Suggest a plausible mech-
anism that is consistent with the rate law. (Hint:
Assume that the oxygen atom is the intermediate.)
Transcribed Image Text:7. 13.74 The following data were collected for the reaction between hydrogen and nitric oxide at 700°C: Experiment 1 2 3 2H₂(g) + 2NO(g) →→ 2H₂O(g) + N₂(8) curied out at 430°C [H₂] 0.010 0.0050 0.010 [NO] 0.025 0.025 0.0125 Initial Rate (M/s) 2.4 x 10-6 1.2 × 10-6 0.60 × 10-6 (a) Determine the order of the reaction. (b) Calcu- late the rate constant. (c) Suggest a plausible mech- anism that is consistent with the rate law. (Hint: Assume that the oxygen atom is the intermediate.)
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