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7) The o-complex formed for the bromination of benzoic acid should be Br. H. .COOH .COOH СООН Br .COOH (а) (b) (c) (d) H. +

7) The o-complex formed for the bromination of benzoic acid should be Br. H. .COOH .COOH СООН Br .COOH (а) (b) (c) (d) H. +

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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9) What would be the chemical shift and spin-splitting ('H NMR) for hydrogens circled in the following compound? A (CH3 (a) A = 5.5 ppm, quartet; B = 2.2 ppm, singlet (c) A = 4.5 ppm, quintet; B = 1.2 ppm, doublet (d) A = 5.5 ppm, quartet; B =2.2 ppm, double %3D (b) A = 4.5, quartet; B = 1.2 ppm, singlet 10) Which of the following compounds would contain characteristic IR stretches at 3300 and 2170 cm-1? A) CH3CH2CHO B) CH3CH=CHCH2OH C) (CH3)2CHC=N (D) CH3CH2CH2C=CH E) CH3C=CCH2CH3 aing 11) Which compound would be expected to show intense IR absorption at 1660 cm-1? A) CH3CH2OCH2CH3 C) CH3CO2CH2CH3 yi B) CH3CH2C=N ) CH3CH2CONH2 E) CH3COCH2CH3 12) What major functional groups are represented in the following IR spectrum? (6) 1
Transcribed Image Text:9) What would be the chemical shift and spin-splitting ('H NMR) for hydrogens circled in the following compound? A (CH3 (a) A = 5.5 ppm, quartet; B = 2.2 ppm, singlet (c) A = 4.5 ppm, quintet; B = 1.2 ppm, doublet (d) A = 5.5 ppm, quartet; B =2.2 ppm, double %3D (b) A = 4.5, quartet; B = 1.2 ppm, singlet 10) Which of the following compounds would contain characteristic IR stretches at 3300 and 2170 cm-1? A) CH3CH2CHO B) CH3CH=CHCH2OH C) (CH3)2CHC=N (D) CH3CH2CH2C=CH E) CH3C=CCH2CH3 aing 11) Which compound would be expected to show intense IR absorption at 1660 cm-1? A) CH3CH2OCH2CH3 C) CH3CO2CH2CH3 yi B) CH3CH2C=N ) CH3CH2CONH2 E) CH3COCH2CH3 12) What major functional groups are represented in the following IR spectrum? (6) 1
7) The o-complex formed for the bromination of benzoic acid should be Br. .COOH .COOH .COOH Br СООН (a) (b) (c) H- + (d) H. Br Br 8) Which one of the bicyclotriene isomers shows the strongest UV absorption band (i.e. with longest wave length) due the most stable form? (a) (b) (c) (d) 1 Period: Time:
Transcribed Image Text:7) The o-complex formed for the bromination of benzoic acid should be Br. .COOH .COOH .COOH Br СООН (a) (b) (c) H- + (d) H. Br Br 8) Which one of the bicyclotriene isomers shows the strongest UV absorption band (i.e. with longest wave length) due the most stable form? (a) (b) (c) (d) 1 Period: Time:
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