650.0 mL of HBr gas at 21.0 °C and 1025 mm Hg is absorbed completely into a solution that was created by mixing 7.147 g of Na2CO3 and 250.0 g of water. (a) What is the pH of the solution? (b) What is the freezing point of the solution?
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650.0 mL of HBr gas at 21.0 °C and 1025 mm Hg is absorbed completely into a solution that was created by mixing 7.147 g of Na2CO3 and 250.0 g of water.
(a) What is the pH of the solution?
(b) What is the freezing point of the solution?
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- 7) An aqueous solution containing 25.0 mg of a hormone in 150.0 mL of solution with an osmotic pressure at 25 °C of 9.00 mmHg. What is the molecular weight of the hormone? 8) (a) What is the pH of a solution in which 45 mL of 0.10 M sodium hydroxide is added to 25mL of 0.15M hydrochloric acid? (b) A brand of carbonated beverage has a pH of 3.50. Calculate [H*]=?A 0.018 M solution of salicylic acid, HOC6H4CO2H, has the same pH as 0.0038 M HNO3solution. (a) Write an equation for the ionization of salicylic acid in aqueous solution. (Assume only the –CO2H portion of the molecule ionizes.) (b) What is the pH of solution containing 0.018 M salicylic acid? (c) Calculate the Ka of salicylic acid.The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10^–8. (a) The undiluted bleach contains roughly 1 M NaClO. Calculate the pH of 1 M NaClO solution. (b) Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000 -fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation. (c) Suppose the solution in (a) is diluted by 1 million-fold, briefly explain how your approach will be different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.
- You are given two glasses of water that have different temperatures. The temperature of the first glass is at 298 K, while the second glass has a temperature of 303 K. It has been determined that the Kw value for the second glass of water is 1.47 x 10-¹4. Which of the following statements is true? (a) The pH of the room temperature glass is higher, but both glasses have the same acidity. (b) The room temperature glass of water has a higher pH, and is more basic than the other glass of water. (c) Both glasses of water are neutral, so both will have a pH of 7.00. (d) The room temperature water has a lower pH, so is more acidic. (e) The warmer glass of water has a lower pH, and is more acidic than the other glass of water.24. A solution of volume 0.500 L contains 1.68 g NH3 and 4.05 g (NH4)2SO4. (a) What is the pH of this solution? (b) If 0.88 g NaOH is added to the solution, what will be the pH? (c) How many milliliters of 12 M HCl must be added to 0.500 L of the original solution to change its pH to 9.00?Propionic acid, HC3H5O2, has Ka= 1.34 x 10–5. (a) What is the molar concentration of H3O+ in 0.15 M HC3H5O2 and the pH of the solution? (b) What is the Kb value for the propionate ion, C3H5O2–? (c) Calculate the pH of 0.15 M solution of sodium propionate, NaC3H5O2. (d) Calculate the pH of solution that contains 0.12 M HC3H5O2 and 0.25 M NaC3H5O2.
- The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10–8. (a)The undiluted bleach contains roughly 1 M NaClO. Calculate the pH of 1 M NaClO solution. (b)Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000 -fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation. (c)Suppose the solution in (a) is diluted by 1million-fold, briefly explain how your approach will be different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.The active ingredient of bleach such as Clorox is sodium hypochlorite (NaClO). Its conjugate acid, hypochlorous acid (HClO), has a Ka of 3.0 × 10–8. (a) The undiluted bleach contains roughly 1 M NaClO.Calculate the pH of 1 M NaClO solution. (b) Some applications require extremely diluted bleach solution, such as swimming pools. Suppose the solution in (a) is diluted by 10,000-fold. Calculate the pH of the diluted solution, and demonstrate that you can still neglect the autoionization of water in your calculation. (c) Suppose the solution in (a) is diluted by 1 million-fold, briefly explain how your approach willbe different. Write the equation with [H3O+] as the unknown, but you do not need to solve it.Determine the pH of (a) A 0.10 M CH3COOH solution (ICE) (b) A solution that is 0.10 M CH3COOH and 0.10 M CH3COONa. Ka for CH3COOH = 1.8 X 10-5.
- 8. (a) HA(aq) is a weak acid with a dissociation constant, Ka, of 8.8 x 10−12. What is the pH of a 0.022 M solution of A−(aq)? The temperature is 25 ◦C. (b) For the reaction A(g) =A(l), the equilibrium constant is 0.666 at 25.0 ◦C and 0.222 at 75.0 ◦C. Making the approximation that the entropy and enthalpy changes of this reaction do not change with temperature, at what temperature will the equilibrium constant be equal to 0.777?The pH of an aqueous solution of 0.400 M hydrocyanic acid, (Ka (HCN) = 4.00 × 10-10) isThe pH of an aqueous solution of 0.289 M ammonium iodide, NH4I (aq), is This solution is