6.4 Stability constants (logio K₁) for complex formation between some 2+ metal cations and sulphate (SO4²- ) and thiosulphate (S₂O3²- ) are tabulated below. On the basis of these data, classify the three cations according to the "Hard and Soft Acids and Bases" principle. Which do you expect to be the donor atom of the thiosulphate in each case? logio K₁(SO₂2²) log10 K₁(S₂O3²-) Ca²+ 2.3 0.4 Co²+ 0.8 0.8 Cd²+ 0.7 2.5

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6.4 Stability constants (logio K₁) for complex formation between some 2+ metal cations
and sulphate (SO²) and thiosulphate (S₂O3²- ) are tabulated below. On the basis of
these data, classify the three cations according to the "Hard and Soft Acids and
Bases" principle. Which do you expect to be the donor atom of the thiosulphate in
each case?
log10 K₁(SO₂²-)
log10 K₁(S₂O3²-)
Ca²+
2.3
0.4
Co²+
0.8
0.8
Cd²+
0.7
2.5
Transcribed Image Text:6.4 Stability constants (logio K₁) for complex formation between some 2+ metal cations and sulphate (SO²) and thiosulphate (S₂O3²- ) are tabulated below. On the basis of these data, classify the three cations according to the "Hard and Soft Acids and Bases" principle. Which do you expect to be the donor atom of the thiosulphate in each case? log10 K₁(SO₂²-) log10 K₁(S₂O3²-) Ca²+ 2.3 0.4 Co²+ 0.8 0.8 Cd²+ 0.7 2.5
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