Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**6.4 Draw the curved arrows that result in the resonance structures below.**
**Structure (c):**
This resonance structure consists of a carbonyl compound with a nitrogen atom. On the left, the oxygen atom is double-bonded to a carbon, and the nitrogen atom carries a negative charge. The resonance structure on the right shows the lone pairs on the nitrogen forming a double bond with the carbon, while the double bond between the oxygen and carbon becomes a single bond, resulting in the oxygen carrying a negative charge. The structures are enclosed in brackets, indicating resonance, and a double-headed arrow between them shows they are resonance forms of the same compound.
**Structure (d):**
This resonance structure involves a five-membered ring resembling a cyclopentadienyl cation. It shows two resonance forms. The left structure has a positive charge on one of the carbon atoms within the ring. The right structure shifts the positive charge to an adjacent carbon atom in the ring, suggesting electron delocalization. The structures are enclosed in brackets, and a double-headed arrow indicates resonance between these forms.
These representations depict electron movement within the molecules, providing insight into resonance stabilization.
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