6. Thallium (1) is oxidized by cerium (IV) as follows: TI+ + 2Ce+4 → TI+3 + 2Ce+3 The elementary steps, in the presence of Mn(II), are: Step 1: Mn+2+ Ce+4 → Mn+³+ Ce+3 Mn+3+ Ce+4 → Mn+4 + Ce+3 TI++ Mn+4 → Mn+² +TI+3 Step 2: Step 3: Identify the catalyst, intermediates and the rate- determining step if the rate law is rate=k[Ce+4] [Mn+²].

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6. Thallium (1) is oxidized by cerium (IV) as follows:
TI+ + 2Ce+4 → TI+³+ 2Ce+3
The elementary
Step 1:
Step 2:
Step 3:
steps, in the presence of Mn(II), are:
Mn +2 + Ce+4 → Mn+³ + Ce+3
Mn+3 + Ce+4 → Mn+4 + Ce+3
TI+ + Mn+4 → Mn+² +TI+³
Identify the catalyst, intermediates and the rate-
determining step if the rate law is rate=k[Ce+4] [Mn +2].
Transcribed Image Text:6. Thallium (1) is oxidized by cerium (IV) as follows: TI+ + 2Ce+4 → TI+³+ 2Ce+3 The elementary Step 1: Step 2: Step 3: steps, in the presence of Mn(II), are: Mn +2 + Ce+4 → Mn+³ + Ce+3 Mn+3 + Ce+4 → Mn+4 + Ce+3 TI+ + Mn+4 → Mn+² +TI+³ Identify the catalyst, intermediates and the rate- determining step if the rate law is rate=k[Ce+4] [Mn +2].
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