6. Consider the following reaction(Criegee Ozonolysis) k 302 203 (Fast) C„H4 + O3 k2 C2H,O3 (Slow) Using the steady-state approximation and pre-equilibrium approximation, calculate the reaction speed of both reactions. Also, find the condition that those two approximations become equivalent.

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In this question, using the steady-state approximation assuming that [O3] is steady throughout, should I consider three reaction speeds (k1, k-1, k2) equivalent, or should I double the reaction speed of ozone production (3O2 → 2O3)?

In other words, is -d[O3]/dt = k1[O2]3 - k-1[O3]2 - k2[O3] = 0, true or false?

6. Consider the following reaction(Criegee Ozonolysis)
k
302
203 (Fast)
C„H4 + O3
k2
C2H,O3 (Slow)
Using the steady-state approximation and pre-equilibrium approximation, calculate the
reaction speed of both reactions. Also, find the condition that those two approximations
become equivalent.
Transcribed Image Text:6. Consider the following reaction(Criegee Ozonolysis) k 302 203 (Fast) C„H4 + O3 k2 C2H,O3 (Slow) Using the steady-state approximation and pre-equilibrium approximation, calculate the reaction speed of both reactions. Also, find the condition that those two approximations become equivalent.
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