6. Consider the following chemical reaction: 2 NO + 2 H2 → N2 + 2 H20 The following data was collected over three experiments: [NO] (M) 10.0 x 103 [H2] (M) Initial Rate (mol Ls) 5.0 x 105 Experiment 1 2.0 x 10-3 2 10.0 x 103 4.0 x 10-3 10.0 x 105 3 14.0 x 103 2.0 x 103 9.8 x 10-5 a) If rate = k[NO]"[(H2]^ what are the values of m and n? b) What is the value of k (including appropriate units)? c) What is the rate of the reaction when [NO] = 1.3 x 10-² M and [H2] = 6.0x 10-3 M? d) Is it possible this reaction could occur in a single elementary step? Why or why not?
6. Consider the following chemical reaction: 2 NO + 2 H2 → N2 + 2 H20 The following data was collected over three experiments: [NO] (M) 10.0 x 103 [H2] (M) Initial Rate (mol Ls) 5.0 x 105 Experiment 1 2.0 x 10-3 2 10.0 x 103 4.0 x 10-3 10.0 x 105 3 14.0 x 103 2.0 x 103 9.8 x 10-5 a) If rate = k[NO]"[(H2]^ what are the values of m and n? b) What is the value of k (including appropriate units)? c) What is the rate of the reaction when [NO] = 1.3 x 10-² M and [H2] = 6.0x 10-3 M? d) Is it possible this reaction could occur in a single elementary step? Why or why not?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![6. Consider the following chemical reaction:
2 NO + 2 H2 → N2 + 2 H20
The following data was collected over three experiments:
Experiment
[NO] (M)
[H2] (M)
Initial Rate (mol L1 s1)
1
10.0 x 103
2.0 x 10-3
5.0 x 10-5
2
10.0 x 103
4.0 x 10-3
10.0 x 105
14.0 x 103
2.0 x 10-3
9.8 x 10-5
a) If rate = k[NO]™[H2]^ what are the values of m and n?
b) What is the value of k (including appropriate units)?
c) What is the rate of the reaction when [NO] = 1.3 x 10-2 M and [H2] = 6.0 x 10-3 M?
d) Is it possible this reaction could occur in a single elementary step? Why or why not?
7. Consider the hypothetical reaction A → products. The following data was obtained over multiple
experiments by measuring the reaction half life at various initial concentrations of A.
[A]o
t1/2
0.100 M
24.0 min
0.150 M
15.9 min
0.300 M
8.02 min
0.400 M
5.95 min
a) What is the rate law for this reaction (assuming it's either zero order, first order or second order)?
HINT: Try to solve part (a) without calculations!
b) What is the rate constant for this reaction?
8. The degradation of ethyl acetate (EA) is a first order process with t1/2 = 110 min.
a) Fill in the blank: For this reaction, a graph of
vs. time will give a straight line (linear plot).
b) What is the rate constant for the degradation of EA ?
c) What percentage of EA will remain after 440 minutes?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F5ab4ed1e-41f4-4e78-860a-2d825d3ed9a1%2Fa00859ad-22cc-44b0-ac06-a89c99731c02%2Fzx76bdj_processed.jpeg&w=3840&q=75)
Transcribed Image Text:6. Consider the following chemical reaction:
2 NO + 2 H2 → N2 + 2 H20
The following data was collected over three experiments:
Experiment
[NO] (M)
[H2] (M)
Initial Rate (mol L1 s1)
1
10.0 x 103
2.0 x 10-3
5.0 x 10-5
2
10.0 x 103
4.0 x 10-3
10.0 x 105
14.0 x 103
2.0 x 10-3
9.8 x 10-5
a) If rate = k[NO]™[H2]^ what are the values of m and n?
b) What is the value of k (including appropriate units)?
c) What is the rate of the reaction when [NO] = 1.3 x 10-2 M and [H2] = 6.0 x 10-3 M?
d) Is it possible this reaction could occur in a single elementary step? Why or why not?
7. Consider the hypothetical reaction A → products. The following data was obtained over multiple
experiments by measuring the reaction half life at various initial concentrations of A.
[A]o
t1/2
0.100 M
24.0 min
0.150 M
15.9 min
0.300 M
8.02 min
0.400 M
5.95 min
a) What is the rate law for this reaction (assuming it's either zero order, first order or second order)?
HINT: Try to solve part (a) without calculations!
b) What is the rate constant for this reaction?
8. The degradation of ethyl acetate (EA) is a first order process with t1/2 = 110 min.
a) Fill in the blank: For this reaction, a graph of
vs. time will give a straight line (linear plot).
b) What is the rate constant for the degradation of EA ?
c) What percentage of EA will remain after 440 minutes?
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