50 ppm .00 ppm 50 ppm 100

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter30: Kinetic Methods Of Analysis
Section: Chapter Questions
Problem 30.2QAP
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Using the data and formula shown,

  • Determine the concentration of iron in the sample and its standard deviation from the least-squares equation of the line.
  • Compare the unknown concentration to that obtained manually from a calibration curve.
CMnO4
1.00 ppm
2.50 ppm
5.00 ppm
7.50 ppm
10.00 ppm
15.00 ppm
20.00 ppm
25.00 ppm
unknown
Absorbance at 580 nm
0.030
0.072
0.147
0.217
0.301
0.442
0.577
0.738
0.356
Transcribed Image Text:CMnO4 1.00 ppm 2.50 ppm 5.00 ppm 7.50 ppm 10.00 ppm 15.00 ppm 20.00 ppm 25.00 ppm unknown Absorbance at 580 nm 0.030 0.072 0.147 0.217 0.301 0.442 0.577 0.738 0.356
The standard deviation about regression,
-
N-2
The standard deviation of the slope.
E
The standard deviation of the intercept,
| Nax - (Σκ)
N
SSesid=[-(b + mx)]²
·Ž[x-
m-Sax
1
N - (Σx)/Σx
Transcribed Image Text:The standard deviation about regression, - N-2 The standard deviation of the slope. E The standard deviation of the intercept, | Nax - (Σκ) N SSesid=[-(b + mx)]² ·Ž[x- m-Sax 1 N - (Σx)/Σx
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