50 mL of 0.005 M Ca²+ solution buffered at pH 10 is to be titrated with 0.01 M EDTA solution. Table 1 shows volume of EDTA added and the corresponding PCA values. Calculate pCa of a, b, c and d. The dissociation coefficient, kf for CaY²- is 5.0 x 10¹⁰. The composition of EDTA solution as a function of pH are shown in Figure 1. Table 1: Volume of EDTA vs pCa
50 mL of 0.005 M Ca²+ solution buffered at pH 10 is to be titrated with 0.01 M EDTA solution. Table 1 shows volume of EDTA added and the corresponding PCA values. Calculate pCa of a, b, c and d. The dissociation coefficient, kf for CaY²- is 5.0 x 10¹⁰. The composition of EDTA solution as a function of pH are shown in Figure 1. Table 1: Volume of EDTA vs pCa
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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
Transcribed Image Text:50 mL of 0.005 M Ca²+ solution buffered at pH 10 is to be titrated with 0.01 M EDTA
solution. Table 1 shows volume of EDTA added and the corresponding pCA values.
Calculate pCa of a, b, c and d. The dissociation coefficient, kf for CaY² is 5.0 x 10¹⁰.
The composition of EDTA solution as a function of pH are shown in Figure 1.
Table 1: Volume of EDTA vs pCa
Vol. EDTA (mL)
pCa
0.0
5.0
10.0
15.0
25.0
26.0
40.0
45.0
50.0
a
2.44
b
2.81
с
8.85
d
10.15
10.24

Transcribed Image Text:1.0
H₂Y²-
HY³-
0000
Y4-
H₂Y-
70
0.8
0.6
0.4
0.2
0
8
2
4
6
8
10
12
14
pH
Figure 1. Composition of EDTA solutions as a function of pH.
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