5.2 The potential energy of two atoms in a molecule can sometimes be approximated by the Morse function, (r) (R- = = A [(e³à¯n\/S − 1)² - 1] where r is the distance between the two atoms and A, R, and S are positive constants with S « R. Sketch this function for 0 < r < ∞. Find the equilibrium separation ro, at which U (r) is minimum. Now write r = ro + x so that x is the displacement from equilibrium, and show that, for small displacements, U has the approximate form U = const + kx². That is, Hooke's law applies. What is the force constant k?
5.2 The potential energy of two atoms in a molecule can sometimes be approximated by the Morse function, (r) (R- = = A [(e³à¯n\/S − 1)² - 1] where r is the distance between the two atoms and A, R, and S are positive constants with S « R. Sketch this function for 0 < r < ∞. Find the equilibrium separation ro, at which U (r) is minimum. Now write r = ro + x so that x is the displacement from equilibrium, and show that, for small displacements, U has the approximate form U = const + kx². That is, Hooke's law applies. What is the force constant k?
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