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5. Which of the following alkyl halides gives the SN2 reaction the fastest? a. C. Br + -Br a. Z- b. cis- c. E- d. trans- b. 6- In which case the order of boiling points of the organic molecules given below is correctly? CH3CH₂F CH3CH3 CH3CH₂Cl a. CH3CH3> CH3CH₂F> CH3CH₂I> CH3CH₂Cl b. CH3CH₂I >CH3CH₂Cl > CH3CH₂F> CH3CH3 c. CH3CH3> CH3CH₂F> CH3CH₂CI> CH3CH₂I d. CH3CH₂F >CH3CH₂Cl > CH3CH₂I > CH3CH3 H₂C a. Dehydration b. Saponification c. Esterification d. Neutralization d. HO 7. In which case the configuration of the following compound is given correctly? -Br CH3 Br CH₂OH CH3CH₂I 8. The reaction of carboxylic acids with alcohols catalysed by conc. H₂SO4 is called 9. Which of the following reagents should be used to perform the following reactions? H3C. a. b. C. d. a. b. C. d. A ? OH i K₂Cr2O7, H₂SO4 PCC, CH₂Cl₂ KMnO4, H₂SO4 PCC, CH₂Cl2 B ?i ? ? il H3C. 10. In which reactions are the reagents appropriate to the question mark given correctly in the following reactions? OH OH H₂C. OH A H₂O/H* H₂O H₂O/H* KMnO4, OH cold H₂ H₂ H₂ H₂ ii LIAIH KMnO4, H₂SO4 PCC, CH₂Cl₂ PCC, CH₂Cl2 OH B KMnO4, OH, heat KMnO4, OH cold KMnO4, OH cold H₂O/H™ 11. Which of the following statements is correct for alkyl halide? a. Alkyl halide will always show SN1 mechanism b. As branching at carbon increases, El mechanism is favoured as compared to SN1 mechanism c. In unimolecular reaction, increasing the temperature do not favours E mechanism d. In most unimolecular reactions of alkyl halide E1 reaction is favoured over SN1 reaction

5. Which of the following alkyl halides gives the SN2 reaction the fastest? a. C. Br + -Br a. Z- b. cis- c. E- d. trans- b. 6- In which case the order of boiling points of the organic molecules given below is correctly? CH3CH₂F CH3CH3 CH3CH₂Cl a. CH3CH3> CH3CH₂F> CH3CH₂I> CH3CH₂Cl b. CH3CH₂I >CH3CH₂Cl > CH3CH₂F> CH3CH3 c. CH3CH3> CH3CH₂F> CH3CH₂CI> CH3CH₂I d. CH3CH₂F >CH3CH₂Cl > CH3CH₂I > CH3CH3 H₂C a. Dehydration b. Saponification c. Esterification d. Neutralization d. HO 7. In which case the configuration of the following compound is given correctly? -Br CH3 Br CH₂OH CH3CH₂I 8. The reaction of carboxylic acids with alcohols catalysed by conc. H₂SO4 is called 9. Which of the following reagents should be used to perform the following reactions? H3C. a. b. C. d. a. b. C. d. A ? OH i K₂Cr2O7, H₂SO4 PCC, CH₂Cl₂ KMnO4, H₂SO4 PCC, CH₂Cl2 B ?i ? ? il H3C. 10. In which reactions are the reagents appropriate to the question mark given correctly in the following reactions? OH OH H₂C. OH A H₂O/H* H₂O H₂O/H* KMnO4, OH cold H₂ H₂ H₂ H₂ ii LIAIH KMnO4, H₂SO4 PCC, CH₂Cl₂ PCC, CH₂Cl2 OH B KMnO4, OH, heat KMnO4, OH cold KMnO4, OH cold H₂O/H™ 11. Which of the following statements is correct for alkyl halide? a. Alkyl halide will always show SN1 mechanism b. As branching at carbon increases, El mechanism is favoured as compared to SN1 mechanism c. In unimolecular reaction, increasing the temperature do not favours E mechanism d. In most unimolecular reactions of alkyl halide E1 reaction is favoured over SN1 reaction

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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5. Which of the following alkyl halides gives the SN2 reaction the fastest? a. C. Br + -Br a. Z- b. cis- c. E- d. trans- b. 6- In which case the order of boiling points of the organic molecules given below is correctly? CH3CH₂F CH3CH3 CH3CH₂Cl a. CH3CH3> CH3CH₂F> CH3CH₂I> CH3CH₂Cl b. CH3CH₂I >CH3CH₂Cl > CH3CH₂F> CH3CH3 c. CH3CH3> CH3CH₂F> CH3CH₂CI> CH3CH₂I d. CH3CH₂F >CH3CH₂Cl > CH3CH₂I > CH3CH3 H₂C a. Dehydration b. Saponification c. Esterification d. Neutralization d. HO 7. In which case the configuration of the following compound is given correctly? -Br CH3 Br CH₂OH CH3CH₂I 8. The reaction of carboxylic acids with alcohols catalysed by conc. H₂SO4 is called 9. Which of the following reagents should be used to perform the following reactions? H3C. a. b. C. d. a. b. C. d. A ? OH i K₂Cr2O7, H₂SO4 PCC, CH₂Cl₂ KMnO4, H₂SO4 PCC, CH₂Cl2 B ?i ? ? il H3C. 10. In which reactions are the reagents appropriate to the question mark given correctly in the following reactions? OH OH H₂C. OH A H₂O/H* H₂O H₂O/H* KMnO4, OH cold H₂ H₂ H₂ H₂ ii LIAIH KMnO4, H₂SO4 PCC, CH₂Cl₂ PCC, CH₂Cl2 OH B KMnO4, OH, heat KMnO4, OH cold KMnO4, OH cold H₂O/H™ 11. Which of the following statements is correct for alkyl halide? a. Alkyl halide will always show SN1 mechanism b. As branching at carbon increases, El mechanism is favoured as compared to SN1 mechanism c. In unimolecular reaction, increasing the temperature do not favours E mechanism d. In most unimolecular reactions of alkyl halide E1 reaction is favoured over SN1 reaction
Transcribed Image Text:5. Which of the following alkyl halides gives the SN2 reaction the fastest? a. C. Br + -Br a. Z- b. cis- c. E- d. trans- b. 6- In which case the order of boiling points of the organic molecules given below is correctly? CH3CH₂F CH3CH3 CH3CH₂Cl a. CH3CH3> CH3CH₂F> CH3CH₂I> CH3CH₂Cl b. CH3CH₂I >CH3CH₂Cl > CH3CH₂F> CH3CH3 c. CH3CH3> CH3CH₂F> CH3CH₂CI> CH3CH₂I d. CH3CH₂F >CH3CH₂Cl > CH3CH₂I > CH3CH3 H₂C a. Dehydration b. Saponification c. Esterification d. Neutralization d. HO 7. In which case the configuration of the following compound is given correctly? -Br CH3 Br CH₂OH CH3CH₂I 8. The reaction of carboxylic acids with alcohols catalysed by conc. H₂SO4 is called 9. Which of the following reagents should be used to perform the following reactions? H3C. a. b. C. d. a. b. C. d. A ? OH i K₂Cr2O7, H₂SO4 PCC, CH₂Cl₂ KMnO4, H₂SO4 PCC, CH₂Cl2 B ?i ? ? il H3C. 10. In which reactions are the reagents appropriate to the question mark given correctly in the following reactions? OH OH H₂C. OH A H₂O/H* H₂O H₂O/H* KMnO4, OH cold H₂ H₂ H₂ H₂ ii LIAIH KMnO4, H₂SO4 PCC, CH₂Cl₂ PCC, CH₂Cl2 OH B KMnO4, OH, heat KMnO4, OH cold KMnO4, OH cold H₂O/H™ 11. Which of the following statements is correct for alkyl halide? a. Alkyl halide will always show SN1 mechanism b. As branching at carbon increases, El mechanism is favoured as compared to SN1 mechanism c. In unimolecular reaction, increasing the temperature do not favours E mechanism d. In most unimolecular reactions of alkyl halide E1 reaction is favoured over SN1 reaction
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