5. Which of the following alkyl halides gives the SN2 reaction the fastest? a. C. -Br a. Z- b. cis- c. E- d. trans- b. 6- In which case the order of boiling points of the organic molecules given below is correctly? CH3CH₂F CH₂CH3 CH₂CH₂Cl a. CH₂CH₂ CH3CH₂F> CH3CH₂I> CH₂CH₂Cl b. CH3CH₂I >CH3CH₂Cl > CH3CH₂F> CH3CH3 c.CH3CH3> CH3CH₂F> CH3CH₂CI> CH₂CH₂I d. CH3CH₂F >CH3CH₂Cl>CH3CH₂I> CH3CH3 H₂C a. Dehydration b. Saponification c. Esterification d. Neutralization d. HO 7. In which case the configuration of the following compound is given correctly? Br CH3 Br CH₂OH CH₂CH₂I 8. The reaction of carboxylic acids with alcohols. catalysed by conc. H₂SO4 is called 9. Which of the following reagents should be used to perform the following reactions? a. b. c. d. H₂ a. b. C. H₂ d. OH 71 i K₂Cr2O7, H₂SO4 PCC, CH₂Cl₂ KMnO4, H₂SO4 PCC, CH₂Cl2 10. In which reactions are the reagents appropriate to the question mark given correctly in the following reactions? OH OH OH A H2O/Ht H₂O H₂O/H* H₂ KMnO4, OH'cold H₂ ii LIAIH4 KMnO4, H₂SO4 PCC, CH₂Cl₂ PCC, CH₂Cl₂ B KMnO4, OH, heat KMnO4, OH cold KMnO4, OH cold H₂O/H 11. Which of the following statements is correct for alkyl halide? a. Alkyl halide will always show SN1 mechanism b. As branching at carbon increases, El mechanism is favoured as compared to SN1 mechanism c. In unimolecular reaction, increasing the temperature do not favours E mechanism d. In most unimolecular reactions of alkyl halide E1
5. Which of the following alkyl halides gives the SN2 reaction the fastest? a. C. -Br a. Z- b. cis- c. E- d. trans- b. 6- In which case the order of boiling points of the organic molecules given below is correctly? CH3CH₂F CH₂CH3 CH₂CH₂Cl a. CH₂CH₂ CH3CH₂F> CH3CH₂I> CH₂CH₂Cl b. CH3CH₂I >CH3CH₂Cl > CH3CH₂F> CH3CH3 c.CH3CH3> CH3CH₂F> CH3CH₂CI> CH₂CH₂I d. CH3CH₂F >CH3CH₂Cl>CH3CH₂I> CH3CH3 H₂C a. Dehydration b. Saponification c. Esterification d. Neutralization d. HO 7. In which case the configuration of the following compound is given correctly? Br CH3 Br CH₂OH CH₂CH₂I 8. The reaction of carboxylic acids with alcohols. catalysed by conc. H₂SO4 is called 9. Which of the following reagents should be used to perform the following reactions? a. b. c. d. H₂ a. b. C. H₂ d. OH 71 i K₂Cr2O7, H₂SO4 PCC, CH₂Cl₂ KMnO4, H₂SO4 PCC, CH₂Cl2 10. In which reactions are the reagents appropriate to the question mark given correctly in the following reactions? OH OH OH A H2O/Ht H₂O H₂O/H* H₂ KMnO4, OH'cold H₂ ii LIAIH4 KMnO4, H₂SO4 PCC, CH₂Cl₂ PCC, CH₂Cl₂ B KMnO4, OH, heat KMnO4, OH cold KMnO4, OH cold H₂O/H 11. Which of the following statements is correct for alkyl halide? a. Alkyl halide will always show SN1 mechanism b. As branching at carbon increases, El mechanism is favoured as compared to SN1 mechanism c. In unimolecular reaction, increasing the temperature do not favours E mechanism d. In most unimolecular reactions of alkyl halide E1
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:5. Which of the following alkyl halides gives the SN2
reaction the fastest?
a.
C.
Br
tor
Br
a. Z-
b. cis-
c. E-
d. trans-
b.
6- In which case the order of boiling points of the
organic molecules given below is correctly?
CH3CH₂F CH3CH3 CH₂CH₂Cl CH3CH₂I
a. CH₂CH₂> CH3CH₂F> CH3CH₂I> CH₂CH₂Cl
b. CH3CH₂I >CH3CH₂Cl > CH3CH₂F> CH3CH3
c. CH3CH3> CH3CH₂F> CH3CH₂Cl> CH3CH₂I
d. CH3CH₂F >CH3CH₂C1> CH3CH₂I > CH3CH3
H₂C
a. Dehydration
b. Saponification
c. Esterification
d. Neutralization
d.
7. In which case the configuration of the following
compound is given correctly?
HO
Br
CH3
'Br
CH₂OH
8. The reaction of carboxylic acids with alcohols
catalysed by conc. H₂SO4 is called
9. Which of the following reagents should be used to
perform the following reactions?
H₂C
a.
b.
C.
d.
H₂
a.
b.
C.
H₂
d.
A?
OH
i
K₂Cr2O7, H₂SO4
PCC, CH₂Cl₂
KMnO4, H₂SO4
PCC, CH₂Cl₂
B
71
?
? 11
10. In which reactions are the reagents appropriate to
the question mark given correctly in the following
reactions?
H₂C
OH OH
H₂C.
OH
A
H₂O/H*
H₂O
H₂O/H+
KMnO4, OH-'cold
H₂
H₂
ii
LIAIH4
KMnO4, H₂SO4
PCC, CH₂Cl₂
PCC, CH₂Cl₂
OH
B
KMnO4, OH, heat
KMnO4, OH cold
KMnO4, OH cold
H₂O/H™
11. Which of the following statements is correct for
alkyl halide?
a. Alkyl halide will always show SN1 mechanism
b. As branching at carbon increases, El mechanism is
favoured as compared to SN1 mechanism
c. In unimolecular reaction, increasing the temperature
do not favours E mechanism
d. In most unimolecular reactions of alkyl halide E1
reaction is favoured over SN1 reaction
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