5. Draw the combining atomic orbitals, in order to obtain the requested molecular orbital. d. е. f. + +

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Draw the combining atomic orbitals, in order to obtain the requested molecular orbital

### Molecular Orbital Formation

**Task 5**: Draw the combining atomic orbitals to create the specified molecular orbital.

The diagram provided includes several steps depicting the formation of molecular orbitals (MOs) from atomic orbitals (AOs). Below is a detailed explanation of each subpart:

**d.**
1. **Combining AOs**: Two square boxes are shown, each labeled with a "+" sign on the right.
2. **Resulting MO**: The combination produces an oval-shaped molecular orbital with the following characteristics:
   - A small circle at the center labeled with a "+" inside.
   - A larger oval surrounding this small circle with a "-" on the outer side.

**e.**
1. **Combining AOs**: Two square boxes are present, each labeled with a "+" sign on the right.
2. **Resulting MO**: The combination forms two distinct oval-shaped molecular orbitals:
   - The top oval-shaped MO has a "-" sign inside.
   - The bottom oval-shaped MO contains a "+" sign.

**f.**
1. **Combining AOs**: One circular box is shown on the left, labeled with a "-" inside, and one square box on the right labeled with a "+" sign.
2. **Resulting MO**: This combination produces a single oval-shaped molecular orbital:
   - The left side of the oval has a "-" sign inside.
   - The right side of the oval contains a "+" sign.

### Explanation:

In each step, the atomic orbitals (whether they are circles or squares) combine to form molecular orbitals. The signs inside the orbitals (either "+" or "-") indicate the phase of the wave functions involved in the combination. These phases are critical in determining the constructive or destructive interference, thereby shaping the resulting molecular orbitals.

### Diagram Summarization:

- **Part d & f**: Illustrates the formation of sigma (σ) or pi (π) molecular orbitals through constructive/destructive interference.
- **Part e**: Depicts the creation of bonding and antibonding MOs, with distinct phases.

This visual representation is fundamental in understanding how atomic orbitals combine to form molecular orbitals, which is a crucial concept in molecular chemistry.
Transcribed Image Text:### Molecular Orbital Formation **Task 5**: Draw the combining atomic orbitals to create the specified molecular orbital. The diagram provided includes several steps depicting the formation of molecular orbitals (MOs) from atomic orbitals (AOs). Below is a detailed explanation of each subpart: **d.** 1. **Combining AOs**: Two square boxes are shown, each labeled with a "+" sign on the right. 2. **Resulting MO**: The combination produces an oval-shaped molecular orbital with the following characteristics: - A small circle at the center labeled with a "+" inside. - A larger oval surrounding this small circle with a "-" on the outer side. **e.** 1. **Combining AOs**: Two square boxes are present, each labeled with a "+" sign on the right. 2. **Resulting MO**: The combination forms two distinct oval-shaped molecular orbitals: - The top oval-shaped MO has a "-" sign inside. - The bottom oval-shaped MO contains a "+" sign. **f.** 1. **Combining AOs**: One circular box is shown on the left, labeled with a "-" inside, and one square box on the right labeled with a "+" sign. 2. **Resulting MO**: This combination produces a single oval-shaped molecular orbital: - The left side of the oval has a "-" sign inside. - The right side of the oval contains a "+" sign. ### Explanation: In each step, the atomic orbitals (whether they are circles or squares) combine to form molecular orbitals. The signs inside the orbitals (either "+" or "-") indicate the phase of the wave functions involved in the combination. These phases are critical in determining the constructive or destructive interference, thereby shaping the resulting molecular orbitals. ### Diagram Summarization: - **Part d & f**: Illustrates the formation of sigma (σ) or pi (π) molecular orbitals through constructive/destructive interference. - **Part e**: Depicts the creation of bonding and antibonding MOs, with distinct phases. This visual representation is fundamental in understanding how atomic orbitals combine to form molecular orbitals, which is a crucial concept in molecular chemistry.
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