5. Consider the combustion reaction of octane (C8H18, mol. wt. = 114.23 g/mol, density = 0.703 g/mL). a. Write out the balanced chemical equation for this reaction. All products are in the gas phase. 2 C8H18 + 25 O2 ---> 16 CO2 + 18 H2O b. Calculate the standard free energy (in kJ/mol) released in this reaction.   ∆Hfo (kJ/mol) Sfo (J/K mol) Octane(l) ─208.4 463.7 H2O(g) ─242 189 02 0 205 CO2(g) ─393.5 214 c. Making the approximation that gasoline consists of 100% octane, how much energy would 1.00 gallon of gasoline release? (1 quart = 946 mL, 1 gallon = 4 quarts)

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5. Consider the combustion reaction of octane (C8H18, mol. wt. = 114.23 g/mol, density = 0.703 g/mL).

a. Write out the balanced chemical equation for this reaction. All products are in the gas phase.

2 C8H18 + 25 O2 ---> 16 CO2 + 18 H2O

b. Calculate the standard free energy (in kJ/mol) released in this reaction.

 

∆Hfo (kJ/mol)

Sfo (J/K mol)

Octane(l)

─208.4

463.7

H2O(g)

─242

189

02

0

205

CO2(g)

─393.5

214

c. Making the approximation that gasoline consists of 100% octane, how much energy would 1.00 gallon of gasoline release? (1 quart = 946 mL, 1 gallon = 4 quarts)

 

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