5. Consider a lattice gas of N particles distributed cells (with N < V). Suppose that each cell may be either empty or occupied by a single particle. The number of microscopic states of this system will be given by among V! N (V, N) = N! (V – N)! Obtain an expression for the entropy per particle, s = s where v = V/N. From this fundamental equation, obtain an expression for the equation of state p/T. Write an expansion of p/T in terms of the density p = 1/v. Show that the first term of this expansion gives the Boyle law of the ideal gases. Sketch a graph of µ/T, where µ is the chemical potential, in terms of Whetia the

5. Consider a lattice gas of N particles distributed cells (with N < V). Suppose that each cell may be either empty or occupied by a single particle. The number of microscopic states of this system will be given by among V! N (V, N) = N! (V – N)! Obtain an expression for the entropy per particle, s = s where v = V/N. From this fundamental equation, obtain an expression for the equation of state p/T. Write an expansion of p/T in terms of the density p = 1/v. Show that the first term of this expansion gives the Boyle law of the ideal gases. Sketch a graph of µ/T, where µ is the chemical potential, in terms of Whetia the

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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