5. A more complex example where other atoms are involved. Balance the following reaction in basic solution. Br (aq) + Mn04 (aq) MnO, (s) + BrO;" (aq)
5. A more complex example where other atoms are involved. Balance the following reaction in basic solution. Br (aq) + Mn04 (aq) MnO, (s) + BrO;" (aq)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![5. A more complex example where other atoms
are involved. Balance the following reaction in
basic solution.
r (aq) + MnO4 (aq)
MnO, (s)+ BrO;" (aq)
TABLE 19.1 Standard Electrode Potentials at 25 °C
Reduction Half-Reaction
E'(V)
F + 20
H,0,(aq) + 2 H(aq)+2 e
2F(aq)
2.87
Stronger
oxidizing agent
Weaker
2 H,0
- PBSO (s) +2 H,0)
-Mn0(s)+ 2 H,0)
Mn (aq) 4 H,O)
- Auts)
1.78
reducing agent
PO,(s) + 4 H"(ag) + S0,2-(aq) + 2 e
1.69
Mno, (aq)+ 4 H'(aq) 3 e
Mno, (aa) + 8 H (aq)+5 e
Au (aq)+3e
PbO,(s)+ 4 H(aa) + 2 e
Cl,(g) + 2 e"
1.68
1.51
1.50
1.46
- P (ag) + 2 HO
- 2a(aq)
1.36
1.33
Cr0, (aq) + 14 H'(ag) + 6 e
0+ 4 H (aq) + 4 e
MnO(s)+4 H'(aq) +2 e
10, (aq) 6 H'(aq) + 5e
Br+2e
vo, (aq) + 2 H'(aq) + e
NO, (aq) + 4 H°(aq) + 3e
CIO+e
2 C"(aq) + 7 H,On
- 2 H,O1)
1.23
Mn (aq) + 2 HyOV)
121
ulae) + 3 H,0()
2 Br (ag)
- vo"(aq) +H,00
- NO + 2 H,O0
- CIO, (aa)
- Agis)
1.20
1.09
1.00
0.96
0.95
Ag"(aa) + e
0.80
Fe (aq) +
O+2 H'(aq)+2e
- Fe*(aq)
0.77
- H,O,(ag)
0.70
Mn0, Taa) + e
Mn0 (aa)
0.56
8) + 2 e
52r(ag)
0.54
Cu'(ag) + e
Cucs)
0.52
O + 2 H,O) + 4e
Cu (aa)+2e
0.40
- Cus)
(be).HO
0.34
- HSO,(ag) + H,00
0.20
so (ao) + 4 H"(aq) + 2 e
Cư* (aq) +e
- Cu'(aa)
0.16
Sn** (ag) + 2 e
S (aq)
0.15
2 H'(ag)+2 e
Fe (ag)+3e
Pb (aq)+2 e
Sn (aq) +2 e
N (aq)+2 e
C (ag)+2 e
Fe (aq) +2e
Cr (ag)+e
Cr"(aq)+3e
Zn (aq)+2 e
2 H,O+2e
Mn (aq)+2 e
AP (ag)+3e
Mg (aq) +2 e
Na (ao)+ e
Ca (ag)+2 e
-Hyl
- Fe(s)
-0.036
- Pb(s)
-0.13
- Snis)
-0.14
- N(s)
-0.23
- Cas)
-0.40
- Fes)
-0.45
- Cr* (ag)
-0.50
- Cris)
--0.73
Znts)
-0.76
- Hyl + 2 0H (aq)
-0.83
Mn(s)
-1.18
- AlS)
-1.66
- Mgis)
-2.37
- Nas)
-2.71
- Cas)
-2.76
Ba (ag) + 2 e
- Ba(s)
-2.90
K (aq) + e
- KIS)
-2.92
Weaker
Stronger
vaducina aannt
avidirina saant
U'lag) +e
U(s)
-3.04](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F84cb7eba-90a4-4eb4-8380-123db5921c14%2Ff2767465-13c3-4938-b164-86e3f2161a4a%2Fpgjarr_processed.jpeg&w=3840&q=75)
Transcribed Image Text:5. A more complex example where other atoms
are involved. Balance the following reaction in
basic solution.
r (aq) + MnO4 (aq)
MnO, (s)+ BrO;" (aq)
TABLE 19.1 Standard Electrode Potentials at 25 °C
Reduction Half-Reaction
E'(V)
F + 20
H,0,(aq) + 2 H(aq)+2 e
2F(aq)
2.87
Stronger
oxidizing agent
Weaker
2 H,0
- PBSO (s) +2 H,0)
-Mn0(s)+ 2 H,0)
Mn (aq) 4 H,O)
- Auts)
1.78
reducing agent
PO,(s) + 4 H"(ag) + S0,2-(aq) + 2 e
1.69
Mno, (aq)+ 4 H'(aq) 3 e
Mno, (aa) + 8 H (aq)+5 e
Au (aq)+3e
PbO,(s)+ 4 H(aa) + 2 e
Cl,(g) + 2 e"
1.68
1.51
1.50
1.46
- P (ag) + 2 HO
- 2a(aq)
1.36
1.33
Cr0, (aq) + 14 H'(ag) + 6 e
0+ 4 H (aq) + 4 e
MnO(s)+4 H'(aq) +2 e
10, (aq) 6 H'(aq) + 5e
Br+2e
vo, (aq) + 2 H'(aq) + e
NO, (aq) + 4 H°(aq) + 3e
CIO+e
2 C"(aq) + 7 H,On
- 2 H,O1)
1.23
Mn (aq) + 2 HyOV)
121
ulae) + 3 H,0()
2 Br (ag)
- vo"(aq) +H,00
- NO + 2 H,O0
- CIO, (aa)
- Agis)
1.20
1.09
1.00
0.96
0.95
Ag"(aa) + e
0.80
Fe (aq) +
O+2 H'(aq)+2e
- Fe*(aq)
0.77
- H,O,(ag)
0.70
Mn0, Taa) + e
Mn0 (aa)
0.56
8) + 2 e
52r(ag)
0.54
Cu'(ag) + e
Cucs)
0.52
O + 2 H,O) + 4e
Cu (aa)+2e
0.40
- Cus)
(be).HO
0.34
- HSO,(ag) + H,00
0.20
so (ao) + 4 H"(aq) + 2 e
Cư* (aq) +e
- Cu'(aa)
0.16
Sn** (ag) + 2 e
S (aq)
0.15
2 H'(ag)+2 e
Fe (ag)+3e
Pb (aq)+2 e
Sn (aq) +2 e
N (aq)+2 e
C (ag)+2 e
Fe (aq) +2e
Cr (ag)+e
Cr"(aq)+3e
Zn (aq)+2 e
2 H,O+2e
Mn (aq)+2 e
AP (ag)+3e
Mg (aq) +2 e
Na (ao)+ e
Ca (ag)+2 e
-Hyl
- Fe(s)
-0.036
- Pb(s)
-0.13
- Snis)
-0.14
- N(s)
-0.23
- Cas)
-0.40
- Fes)
-0.45
- Cr* (ag)
-0.50
- Cris)
--0.73
Znts)
-0.76
- Hyl + 2 0H (aq)
-0.83
Mn(s)
-1.18
- AlS)
-1.66
- Mgis)
-2.37
- Nas)
-2.71
- Cas)
-2.76
Ba (ag) + 2 e
- Ba(s)
-2.90
K (aq) + e
- KIS)
-2.92
Weaker
Stronger
vaducina aannt
avidirina saant
U'lag) +e
U(s)
-3.04
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