5) Which one of the following statements is true? The enthalpy change for a for a reaction is independent of the state of the reactants and products. Enthalpy is a state function. H is the value of q measured under conditions of constant volume. The enthalpy change of a reaction is the reciprocal of the AH of the reverse reaction. Page 2 of 8

Chemistry
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Chapter1: Chemical Foundations
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**Question 5: Determining the True Statement About Enthalpy**

The question focuses on identifying the correct statement related to the concept of enthalpy in thermodynamics.

**Provided Statements:**

1. The enthalpy change for a reaction is independent of the state of the reactants and products.
2. Enthalpy is a state function.
3. \( H \) is the value of \( q \) measured under conditions of constant volume.
4. The enthalpy change of a reaction is the reciprocal of the \( \Delta H \) of the reverse reaction.

**Explanation:**

- **State Function:** A property that depends only on the current state of the system, not on the path taken to reach that state.
- **Enthalpy (\( H \)):** A thermodynamic quantity equivalent to the total heat content of a system, defined as \( H = U + PV \), where \( U \) is the internal energy, \( P \) is pressure, and \( V \) is volume.
- Enthalpy changes in reactions typically occur at constant pressure, not constant volume.
- The enthalpy change (\( \Delta H \)) of a reverse reaction is equal in magnitude but opposite in sign, not reciprocal.

Understanding these concepts is crucial for analyzing thermodynamic processes accurately.
Transcribed Image Text:**Question 5: Determining the True Statement About Enthalpy** The question focuses on identifying the correct statement related to the concept of enthalpy in thermodynamics. **Provided Statements:** 1. The enthalpy change for a reaction is independent of the state of the reactants and products. 2. Enthalpy is a state function. 3. \( H \) is the value of \( q \) measured under conditions of constant volume. 4. The enthalpy change of a reaction is the reciprocal of the \( \Delta H \) of the reverse reaction. **Explanation:** - **State Function:** A property that depends only on the current state of the system, not on the path taken to reach that state. - **Enthalpy (\( H \)):** A thermodynamic quantity equivalent to the total heat content of a system, defined as \( H = U + PV \), where \( U \) is the internal energy, \( P \) is pressure, and \( V \) is volume. - Enthalpy changes in reactions typically occur at constant pressure, not constant volume. - The enthalpy change (\( \Delta H \)) of a reverse reaction is equal in magnitude but opposite in sign, not reciprocal. Understanding these concepts is crucial for analyzing thermodynamic processes accurately.
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