5) What main product(s) would you expect if the following bromide is heated with an excess of ethanol for a prolonged period of time? Ms O Br Br OMS
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- Show the products from reaction of p-bromoaniline with the following reagents: (a) CH3I (excess) (b) HCl (c) HNO2, H2SO4 (d) CH3COCl (e) CH3MgBr (f) CH3CH2Cl, AlCl3 (g) Product of (c) with CuCl, HCl (h) Product of (d) with CH3CH2Cl, AlCl32. What organometallic and carbonyl compound could be used to prepare the following compounds? Propose two different carbonyl starting materials and corresponding organometallic reagents for each compound. HO OHAn acetal produces the following three compounds upon hydrolysis. Of acetals A-E which could it be? H3CO OCH3 П A B U D Acetal A H2O H₂SO4(cat.) замен поста "OCH3 В + HO. H₂CO ОН D + OCH3 CH3OH E OCH3 "OCH3
- The following diol is prepared from propanal (CH3CH2CHO) and 3-bromopropanol. Which derivatives will be among intermediate products in this transformation? ОН HOVII. What Grignard reagent and what carbonyl compound might you start with to prepare the following alcohols? он CH3CH2CHCH2CH3 (a) он (b) (c) CH3 CH3CHCH2CH3 H2C CH2OH (d) (e) HO CH3 (f) CH2OH CH3 ноArrange the following carbonyl compounds in order of increasing reactivity towards nucleophiles with the least reactive first (" NH2 H3C OCH, HC H H3C OH HC H3C CH3 IV VI
- . Which two of the following compounds are the most common reagents for E2- elimination reactions? t-BuOEt t-BUOK Et20 ELONA O Et,O and EtONa t-BuOEt and Et,0 O t-BUOK and t-BuOEt O t-BUOK and ELONAHQ14.33 - Level 2 := X Answered - Incorrect • 2 attempts left How can (R)-2-butanol be converted to (R)-2-methylbutanenitrile? Select all that apply. O Select all that apply Treat (R)-2-butanol with methane sulfonyl chloride followed by treatment with sodium cyanide. Your answer Treat (R)-2-butanol with thionyl chloride and pyridine followed В by treatment with sodium cyanide. Treat (R)-2-butanol with C sodium cyanide. Treat (S)-2-butanol with sodium D cyanide. Treat (R)-2-butanol with phosphorus tribromide E followed by treatment with sodium cyanide.Reaction of phenol with acetone in the presence of an acid catalyst gives a compound known as bisphenol A, which is used in the production of epoxy and polycarbonate resins Propose a mechanism for the formation of bisphenol A. OH H;PO, + H,O НО HO Phenol Acetone Bisphenol A
- 10) Which of the following is (2R, 3S)-2,3-pentanediol? он он он он Он он он ÕH он A B DNH2 HO, H. Atenolol Tenormin® Below is a two-step reaction sequence. What are the steps in the synthesis? `NH2 -NH2 `NH2 base OH OH O The phenolate reacts with the epoxide preferentially over the alkyl halide at the less sterically hindered position. Then, the sterically hindered amine attacks the alkyl chloride. O The phenolate reacts with the epoxide preferentially over the alkyl halide at the more sterically hindered position. Then, the sterically hindered amine attacks the alkyl chloride.Rank the following carbonyl compounds in order of increasing reactivity towards nucleophiles: NH2 I Br II III IV