4930 20) An unknown compound has the chemical formula C4H3O. It's IR spectrum and ¹H NMR spectrum are shown below. Propose a structure for the unknown molecule. Calculate the Degrees of Unsaturation (DU), assign any important peaks in the IR spectrum to vibrational modes and briefly explain why the structure fits the ¹H NMR spectrum that is provided. 2966 11 2937 49 2870 30 2017 G2 2716 $5 1791 4 1464 88 Degrees of unsaturation (show work below): 4872 Du = 12 (417²)-8 2 1000 1469 66 1411 70 1300 72 1302 70 1302 79 1351 79 1204 84 64 1269 36 1822 1214 04 27 1141 1118 74 1000 94 1045 44 29 66 coca 991 01 GSD 75 234 01 043 06 677 BE 672 06 520 81 1721 EMP 613 04 wom партитур www 1350 1000 500 Vibrational Assignments of IR Peaks Wavenumber (cm-¹) Vibrational Assignment C-It Stretch C =0 Stretch 10-8 2 12 HSP-04-071 11 = 9.76 ppm 1H Singlet 13/12 = Brief rationalization for proposed structure: (explain why DU, IR, and NMR are consistent with proposed structure) 0.97 ppm 3H Triplet 1.64 ppm 2H Sextet 2.37 ppm 2H Quadruplet 10 9 8 7 6 5 4 3 2 1 ppm Proposed structure of unknown:
4930 20) An unknown compound has the chemical formula C4H3O. It's IR spectrum and ¹H NMR spectrum are shown below. Propose a structure for the unknown molecule. Calculate the Degrees of Unsaturation (DU), assign any important peaks in the IR spectrum to vibrational modes and briefly explain why the structure fits the ¹H NMR spectrum that is provided. 2966 11 2937 49 2870 30 2017 G2 2716 $5 1791 4 1464 88 Degrees of unsaturation (show work below): 4872 Du = 12 (417²)-8 2 1000 1469 66 1411 70 1300 72 1302 70 1302 79 1351 79 1204 84 64 1269 36 1822 1214 04 27 1141 1118 74 1000 94 1045 44 29 66 coca 991 01 GSD 75 234 01 043 06 677 BE 672 06 520 81 1721 EMP 613 04 wom партитур www 1350 1000 500 Vibrational Assignments of IR Peaks Wavenumber (cm-¹) Vibrational Assignment C-It Stretch C =0 Stretch 10-8 2 12 HSP-04-071 11 = 9.76 ppm 1H Singlet 13/12 = Brief rationalization for proposed structure: (explain why DU, IR, and NMR are consistent with proposed structure) 0.97 ppm 3H Triplet 1.64 ppm 2H Sextet 2.37 ppm 2H Quadruplet 10 9 8 7 6 5 4 3 2 1 ppm Proposed structure of unknown:
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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