4.3.18 VLE of Non-ideal Solution The activity coefficients of benzene (A) - cyclohexane (B) mixtures at 40C are given by RT In YA = br and RT In YB = ba. At 40°C, A and B form an azeotrope containing 49.4. mol % A at a total pressure of 202.6 mm Hg. If the vapor pressures of pure A and B are 182.6 and 183.5 mm Hg respectively, calculate the total pressure of the vapor at 40°C in equilibrium with a liquid mixture containing 12.6 mol % A. %3D

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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4.3.18 VLE of Non-ideal Solution
The activity coefficients of benzene (A) - cyclohexane (B) mixtures at 40C are given by
RT In YA = br and RT In YB = bx. At 40°C, A and B form an azeotrope containing 49.4.
mol % A at a total pressure of 202.6 mm Hg. If the vapor pressures of pure A and B are
182.6 and 183.5 mm Hg respectively, calculate the total pressure of the vapor at 40°C in
equilibrium with a liquid mixture containing 12.6 mol % A.
%3D
Transcribed Image Text:4.3.18 VLE of Non-ideal Solution The activity coefficients of benzene (A) - cyclohexane (B) mixtures at 40C are given by RT In YA = br and RT In YB = bx. At 40°C, A and B form an azeotrope containing 49.4. mol % A at a total pressure of 202.6 mm Hg. If the vapor pressures of pure A and B are 182.6 and 183.5 mm Hg respectively, calculate the total pressure of the vapor at 40°C in equilibrium with a liquid mixture containing 12.6 mol % A. %3D
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