4. The total number of the accessible microscopic states of the Boltzmann gas, with energy E and number of particles N, may be written as N! N(E,N) = E N!N2! - .. with the restrictions EN; = N and DGN; = E. Except for an additive constant, show that the entropy per par- ticle is given by

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4. The total number of the accessible microscopic states of
the Boltzmann gas, with energy E and number of particles N,
may be written as
N!
Ω (Ε, N) = Σ
N!N2! ...
N1.N2.
with the restrictions
EN; = N and
EGN; = E.
Except for an additive constant, show that the entropy per par-
ticle is given by
s = -kB
In
where {Ñ;} is the set of occupation numbers at equilibrium.
Using the continuum limit of the Boltzmann gas, show that the
entropy depends on temperature according to a term of the form
kg In T (note the correction!).
Transcribed Image Text:4. The total number of the accessible microscopic states of the Boltzmann gas, with energy E and number of particles N, may be written as N! Ω (Ε, N) = Σ N!N2! ... N1.N2. with the restrictions EN; = N and EGN; = E. Except for an additive constant, show that the entropy per par- ticle is given by s = -kB In where {Ñ;} is the set of occupation numbers at equilibrium. Using the continuum limit of the Boltzmann gas, show that the entropy depends on temperature according to a term of the form kg In T (note the correction!).
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