4. Sketch a graphical representation of the following events for the equilibrium below. PCls 5 PCle + Cl@ AH =+ 88 kJ/mol a) PCI, is introduced into a flask at t=0 to a concentration of 2 mol/L. b) The flask is heated gently until no further changes in concentration of PCl, occur (5 minutes). At this time, the concentration of PCl,(g) is 1.25 mol/L. c) At t=10 min an additional 0.25 mol/L of chlorine gas is injected into the flask. d) At t=15 min, no further changes in concentration were observed. e) Indicate the places on the graph where the system is at equilibrium.
4. Sketch a graphical representation of the following events for the equilibrium below. PCls 5 PCle + Cl@ AH =+ 88 kJ/mol a) PCI, is introduced into a flask at t=0 to a concentration of 2 mol/L. b) The flask is heated gently until no further changes in concentration of PCl, occur (5 minutes). At this time, the concentration of PCl,(g) is 1.25 mol/L. c) At t=10 min an additional 0.25 mol/L of chlorine gas is injected into the flask. d) At t=15 min, no further changes in concentration were observed. e) Indicate the places on the graph where the system is at equilibrium.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:4. Sketch a graphical representation of the following events for the equilibrium below.
PCIse 5 PCe + Cl
ΔΗ
= + 88 kJ/mol
15(g)
3(g)
2(g)
a) PCI, is introduced into a flask at t=0 to a concentration of 2 mol/L.
b) The flask is heated gently until no further changes in concentration of PCl, occur (5 minutes). At this time, the
concentration of PCl(g) is 1.25 mol/L.
c) At t=10 min an additional 0.25 mol/L of chlorine gas is injected into the flask.
d) At t=15 min, no further changes in concentration were observed.
Indicate the places on the graph where the system is at equilibrium.
f)
Use the information provided to calculate K, the equilibrium constant of this reactions.
Conc'n
(mol/L)
Time (min)
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