Predict and calculate the effect of volume change on an equilibrium system. Consider the equilibrium between PCI, PCI, and Cl₂. PCI, (g) PC13(g) + Cl₂(g) The reaction is allowed to reach equilibrium in a 11.6-L flask. At equilibrium, [PCI5] = 0.107 M, [PCI3] = 9.40×10-2 M and [Cl₂] = 9.40×102 M. (a) The equilibrium mixture is transferred to a 5.80-L flask. In which direction will the reaction proceed to reach equilibrium? K=8.26x10-2 at 537 K (b) Calculate the new equilibrium concentrations that result when the equilibrium mixture is transferred to a 5.80-L flask. [PCI5] = [PCI3] = [Cl₂] ΣΣΣ

Chemistry: The Molecular Science
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Chapter12: Chemical Equilibrium
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Predict and calculate the effect of volume change on an equilibrium system.
Consider the equilibrium between PCI, PCI, and Cl₂.
PCI5(g) PC13(g) + Cl₂(g) K=8.26x10-² at 537 K
The reaction is allowed to reach equilibrium in a 11.6-L flask. At equilibrium, [PCI5] = 0.107 M, [PCI3] =
9.40x102 M and [Cl₂] = 9.40×10² M.
(a) The equilibrium mixture is transferred to a 5.80-L flask. In which direction will the reaction proceed
to reach equilibrium?
(b) Calculate the new equilibrium concentrations that result when the equilibrium mixture is
transferred to a 5.80-L flask.
[PCI,] =
[PCI3] =
[Cz) =
ΣΣΣ
M
Transcribed Image Text:Predict and calculate the effect of volume change on an equilibrium system. Consider the equilibrium between PCI, PCI, and Cl₂. PCI5(g) PC13(g) + Cl₂(g) K=8.26x10-² at 537 K The reaction is allowed to reach equilibrium in a 11.6-L flask. At equilibrium, [PCI5] = 0.107 M, [PCI3] = 9.40x102 M and [Cl₂] = 9.40×10² M. (a) The equilibrium mixture is transferred to a 5.80-L flask. In which direction will the reaction proceed to reach equilibrium? (b) Calculate the new equilibrium concentrations that result when the equilibrium mixture is transferred to a 5.80-L flask. [PCI,] = [PCI3] = [Cz) = ΣΣΣ M
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