Predict and calculate the effect of volume change on an equilibrium system. Consider the equilibrium between PCI, PCI, and Cl₂. PCI, (g) PC13(g) + Cl₂(g) The reaction is allowed to reach equilibrium in a 11.6-L flask. At equilibrium, [PCI5] = 0.107 M, [PCI3] = 9.40×10-2 M and [Cl₂] = 9.40×102 M. (a) The equilibrium mixture is transferred to a 5.80-L flask. In which direction will the reaction proceed to reach equilibrium? K=8.26x10-2 at 537 K (b) Calculate the new equilibrium concentrations that result when the equilibrium mixture is transferred to a 5.80-L flask. [PCI5] = [PCI3] = [Cl₂] ΣΣΣ
Predict and calculate the effect of volume change on an equilibrium system. Consider the equilibrium between PCI, PCI, and Cl₂. PCI, (g) PC13(g) + Cl₂(g) The reaction is allowed to reach equilibrium in a 11.6-L flask. At equilibrium, [PCI5] = 0.107 M, [PCI3] = 9.40×10-2 M and [Cl₂] = 9.40×102 M. (a) The equilibrium mixture is transferred to a 5.80-L flask. In which direction will the reaction proceed to reach equilibrium? K=8.26x10-2 at 537 K (b) Calculate the new equilibrium concentrations that result when the equilibrium mixture is transferred to a 5.80-L flask. [PCI5] = [PCI3] = [Cl₂] ΣΣΣ
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 62QRT
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![Predict and calculate the effect of volume change on an equilibrium system.
Consider the equilibrium between PCI, PCI, and Cl₂.
PCI5(g) PC13(g) + Cl₂(g) K=8.26x10-² at 537 K
The reaction is allowed to reach equilibrium in a 11.6-L flask. At equilibrium, [PCI5] = 0.107 M, [PCI3] =
9.40x102 M and [Cl₂] = 9.40×10² M.
(a) The equilibrium mixture is transferred to a 5.80-L flask. In which direction will the reaction proceed
to reach equilibrium?
(b) Calculate the new equilibrium concentrations that result when the equilibrium mixture is
transferred to a 5.80-L flask.
[PCI,] =
[PCI3] =
[Cz) =
ΣΣΣ
M](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fcab27ebe-ca52-4065-95ad-a0b64c44780e%2F6a6e2c43-7944-4c4f-8e56-4982185d3a35%2Fago9hk9_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Predict and calculate the effect of volume change on an equilibrium system.
Consider the equilibrium between PCI, PCI, and Cl₂.
PCI5(g) PC13(g) + Cl₂(g) K=8.26x10-² at 537 K
The reaction is allowed to reach equilibrium in a 11.6-L flask. At equilibrium, [PCI5] = 0.107 M, [PCI3] =
9.40x102 M and [Cl₂] = 9.40×10² M.
(a) The equilibrium mixture is transferred to a 5.80-L flask. In which direction will the reaction proceed
to reach equilibrium?
(b) Calculate the new equilibrium concentrations that result when the equilibrium mixture is
transferred to a 5.80-L flask.
[PCI,] =
[PCI3] =
[Cz) =
ΣΣΣ
M
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