4. On the basis of your mechanism for Problem 3(c), answer the following questions: (a) Additions of Br₂ and ArSCI to [2.2.1]-bicycloheptene give the products shown in Equa- tions 11 and 12, respectively. Give a mechanism for the products of Reaction 11 and explain why only the bromination gives rearrangement products. Br A.-d.. +Br₂7 Br Br Br ŞAr A.- A + ARSCI CI Br (11) (12)

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4. On the basis of your mechanism for Problem 3(c), answer the following questions:
(a) Additions of Brg and ArSCI to [2.2.1]-bicycloheptene give the products shown in Equa-
tions 11 and 12, respectively. Give a mechanism for the products of Reaction 11 and
explain why only the bromination gives rearrangement products.
Br
ddybde
+
Br
+ Br₂
Br
+ ARSCI
Br
CI
+
SAr
Br
(11)
(12)
Transcribed Image Text:4. On the basis of your mechanism for Problem 3(c), answer the following questions: (a) Additions of Brg and ArSCI to [2.2.1]-bicycloheptene give the products shown in Equa- tions 11 and 12, respectively. Give a mechanism for the products of Reaction 11 and explain why only the bromination gives rearrangement products. Br ddybde + Br + Br₂ Br + ARSCI Br CI + SAr Br (11) (12)
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