4. On the basis of your mechanism for Problem 3(c), answer the following questions: (a) Additions of Br₂ and ArSCI to [2.2.1]-bicycloheptene give the products shown in Equa- tions 11 and 12, respectively. Give a mechanism for the products of Reaction 11 and explain why only the bromination gives rearrangement products. Br A.-d.. +Br₂7 Br Br Br ŞAr A.- A + ARSCI CI Br (11) (12)
4. On the basis of your mechanism for Problem 3(c), answer the following questions: (a) Additions of Br₂ and ArSCI to [2.2.1]-bicycloheptene give the products shown in Equa- tions 11 and 12, respectively. Give a mechanism for the products of Reaction 11 and explain why only the bromination gives rearrangement products. Br A.-d.. +Br₂7 Br Br Br ŞAr A.- A + ARSCI CI Br (11) (12)
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Step 1: Reaction of alkene with bromine molecule
VIEWStep 2: Formation of bromonium ion
VIEWStep 3: Attack of bromide.
VIEWStep 4: Rearrangements and attack of bromide.
VIEWStep 5: Rearrangements and attack of bromide.
VIEWStep 6: Reaction of alkene with ArSCl
VIEWStep 7: Rearrangement in bromination
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