Show the curved-arrow mechanism for the first step, and the structure of the cyclic intermediate formed, when cyclopentene in treated with KMnO4 . A Lewis structure for the permanganate ion is provided in the hint. Make sure to show all non‑bonding electron pairs and formal charges where necessary. Omit K+ .

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Sulfur Functional Groups

Many organic molecules contain sulfur functional groups and have their own importance in chemistry as well as biology. Some of the organic molecules which contain sulfur functional groups and the corresponding sulfur functionality is given below: