4.- Determine the structural relationship between the compounds in each of the pairs that follow. They may be unrelated, identical (the same compound), constitutional isomers, diastereoisomers, enantiomers? - Identify the optically active (chiral) compounds and any meso compounds. - Assign a configuration (R or S) to all stereocenters. - Name all compounds so that the name reflects the structure unambiguously. a) b) c) CHO H- -NH₂ H- HO- -H CH₂OH H CH3 IQ H CH3 CI Ph H CH₂OH -OH HNH2 CHO H3C H I I Ph & I J. CI CH3

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter23: Amines
Section: Chapter Questions
Problem 23.22P
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4.- Determine the structural relationship between the compounds in each of the pairs
that follow. They may be unrelated, identical (the same compound), constitutional
isomers, diastereoisomers, enantiomers?
- Identify the optically active (chiral) compounds and any meso compounds.
- Assign a configuration (R or S) to all stereocenters.
- Name all compounds so that the name reflects the structure unambiguously.
a)
b)
d)
e)
f)
H-
HO H
CHO
CI
H3C
H CH3
H₂
-NH₂
CH₂OH
CH3
H
H
H
CH2OH
-OH
HNH2
CHO
H3C H
coloca
OH
Ph
CH3 H H
Ph
H
CI
H
H
CI
& &
CI
CH3
OH
H3C
O-CH3
O-CH3
OH
Transcribed Image Text:4.- Determine the structural relationship between the compounds in each of the pairs that follow. They may be unrelated, identical (the same compound), constitutional isomers, diastereoisomers, enantiomers? - Identify the optically active (chiral) compounds and any meso compounds. - Assign a configuration (R or S) to all stereocenters. - Name all compounds so that the name reflects the structure unambiguously. a) b) d) e) f) H- HO H CHO CI H3C H CH3 H₂ -NH₂ CH₂OH CH3 H H H CH2OH -OH HNH2 CHO H3C H coloca OH Ph CH3 H H Ph H CI H H CI & & CI CH3 OH H3C O-CH3 O-CH3 OH
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